(E)-[2-{(methoxymethoxy)methyl}phenyl]dimethyl(4,4,4-trifluorobut-1-en-1-yl)silane

Base Information

Chemical Name:(E)-[2-{(methoxymethoxy)methyl}phenyl]dimethyl(4,4,4-trifluorobut-1-en-1-yl)silane
CAS No.:1380233-10-2
Molecular Formula:C₁₅H₂₁F₃O₂Si
Molecular Weight:318.411
Hs Code.:

Synonyms:(E)-[2-{(methoxymethoxy)methyl}phenyl]dimethyl(4,4,4-trifluorobut-1-en-1-yl)silane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (E)-[2-{(methoxymethoxy)methyl}phenyl]dimethyl(4,4,4-trifluorobut-1-en-1-yl)silane

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Technology Process of (E)-[2-{(methoxymethoxy)methyl}phenyl]dimethyl(4,4,4-trifluorobut-1-en-1-yl)silane

There total 3 articles about (E)-[2-{(methoxymethoxy)methyl}phenyl]dimethyl(4,4,4-trifluorobut-1-en-1-yl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: 887144-94-7
Togni's reagent II

: 1380232-83-6
allyl[2-{(methoxymethoxy)methyl}phenyl]dimethylsilane

: 1380233-10-2
(E)-[2-{(methoxymethoxy)methyl}phenyl]dimethyl(4,4,4-trifluorobut-1-en-1-yl)silane

Guidance literature:: With copper(l) iodide; In methanol; at 20 ℃; for 24h; Inert atmosphere;
DOI:10.1002/anie.201201095

Reference yield:

: 94236-21-2
1-bromo-2-((methoxymethoxy)methyl)benzene

: 1380233-10-2
(E)-[2-{(methoxymethoxy)methyl}phenyl]dimethyl(4,4,4-trifluorobut-1-en-1-yl)silane

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C

1.2: -78 - 20 °C

2.1: copper(l) iodide / methanol / 24 h / 20 °C / Inert atmosphere

With copper(l) iodide; n-butyllithium; In tetrahydrofuran; methanol; hexane;
DOI:10.1002/anie.201201095

Reference yield:

: 18982-54-2
o-bromobenzyl alcohol

: 1380233-10-2
(E)-[2-{(methoxymethoxy)methyl}phenyl]dimethyl(4,4,4-trifluorobut-1-en-1-yl)silane

Guidance literature:: Multi-step reaction with 3 steps

1.1: sodium hydride / tetrahydrofuran / 0.5 h / 0 °C

1.2: 1 h

2.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C

2.2: -78 - 20 °C

3.1: copper(l) iodide / methanol / 24 h / 20 °C / Inert atmosphere

With copper(l) iodide; n-butyllithium; sodium hydride; In tetrahydrofuran; methanol; hexane;
DOI:10.1002/anie.201201095