5(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-5'-(trimethylsilyl)-3,4'-dihexyl-2,2'-bithiophene

Base Information

Chemical Name:5(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-5'-(trimethylsilyl)-3,4'-dihexyl-2,2'-bithiophene
CAS No.:1372812-54-8
Molecular Formula:C₂₉H₄₉BO₂S₂Si
Molecular Weight:532.735
Hs Code.:

Synonyms:5(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-5'-(trimethylsilyl)-3,4'-dihexyl-2,2'-bithiophene

Suppliers and Price of 5(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-5'-(trimethylsilyl)-3,4'-dihexyl-2,2'-bithiophene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 5(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-5'-(trimethylsilyl)-3,4'-dihexyl-2,2'-bithiophene

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

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Useful:

Technology Process of 5(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-5'-(trimethylsilyl)-3,4'-dihexyl-2,2'-bithiophene

There total 1 articles about 5(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-5'-(trimethylsilyl)-3,4'-dihexyl-2,2'-bithiophene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 69249-61-2,125321-66-6
3-hexyl-2-bromothiophene

: 1372812-54-8
5(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-5'-(trimethylsilyl)-3,4'-dihexyl-2,2'-bithiophene

Guidance literature:: Multi-step reaction with 2 steps

1: tri tert-butylphosphoniumtetrafluoroborate; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; potassium carbonate / tetrahydrofuran

2: n-butyllithium / tetrahydrofuran

With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; n-butyllithium; potassium carbonate; tri tert-butylphosphoniumtetrafluoroborate; In tetrahydrofuran; 1: |Suzuki Coupling;
DOI:10.3762/bjoc.12.169

Reference yield:

: 1372812-54-8
5(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-5'-(trimethylsilyl)-3,4'-dihexyl-2,2'-bithiophene

: 165550-62-9
N-(2,6-diisopropylphen-yl)-9-bromo-perylene-3,4-dicarboximide

: C₅₇H₆₃NO₂S₂Si

Guidance literature:: With potassium phosphate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In 1,2-dimethoxyethane; water; at 80 ℃; for 1.5h;
DOI:10.1039/c2jm16847b

Reference yield:

: 1372812-54-8
5(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-5'-(trimethylsilyl)-3,4'-dihexyl-2,2'-bithiophene

: 1372812-55-9
5-([N-(2,6-diisopropylphenyl)]-9-perylenyl-3,4-dicarboximide)-3,4'-dihexyl-2,2'-bithiophene

Guidance literature:: Multi-step reaction with 2 steps

1: potassium phosphate; tetrakis(triphenylphosphine) palladium⁽⁰⁾ / 1,2-dimethoxyethane; water / 1.5 h / 80 °C

2: tetrabutyl ammonium fluoride / 2.5 h

With potassium phosphate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; tetrabutyl ammonium fluoride; In 1,2-dimethoxyethane; water; 1: Suzuki coupling;
DOI:10.1039/c2jm16847b