(4S,4aR,7R,7aR)-7-Methoxy-2,2-diMethyl-6-oxo-tetrahydro-4H-furo[3,2-d][1,3]dioxine-4-carbaldehyde

Base Information

Chemical Name:(4S,4aR,7R,7aR)-7-Methoxy-2,2-diMethyl-6-oxo-tetrahydro-4H-furo[3,2-d][1,3]dioxine-4-carbaldehyde
CAS No.:270902-66-4
Molecular Formula:C₁₀H₁₄O₆
Molecular Weight:230.218
Hs Code.:
Mol file:270902-66-4.mol

Synonyms:(4S,4aR,7R,7aR)-7-methoxy-2,2-dimethyl-6-oxotetrahydro-4H-furo[3,2-d][1,3]dioxine-4-carbaldehyde

Suppliers and Price of (4S,4aR,7R,7aR)-7-Methoxy-2,2-diMethyl-6-oxo-tetrahydro-4H-furo[3,2-d][1,3]dioxine-4-carbaldehyde

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (4S,4aR,7R,7aR)-7-Methoxy-2,2-diMethyl-6-oxo-tetrahydro-4H-furo[3,2-d][1,3]dioxine-4-carbaldehyde

Chemical Property:

Purity/Quality:: 99% ^*data from raw suppliers

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Technology Process of (4S,4aR,7R,7aR)-7-Methoxy-2,2-diMethyl-6-oxo-tetrahydro-4H-furo[3,2-d][1,3]dioxine-4-carbaldehyde

There total 5 articles about (4S,4aR,7R,7aR)-7-Methoxy-2,2-diMethyl-6-oxo-tetrahydro-4H-furo[3,2-d][1,3]dioxine-4-carbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 270902-65-3
(4R,4aS,7R,7aR)-4-((R)-1,2-dihydroxyethyl)-7-methoxy-2,2-dimethyltetra-hydro-6H-furo[3,2-d][1,3]dioxin-6-one

: 270902-66-4
(4S,4aR,7R,7aR)-7-methoxy-2,2-dimethyl-6-oxotetrahydro-4H-furo[3,2-d][1,3]dioxine-4-carbaldehyde

Guidance literature:: With sodium periodate; In methanol; water; at 8 ℃; for 0.666667h;
DOI:10.1021/jo0017133

Reference yield:

: 6605-22-7
3,5:6,7-bis-O-(1-methylethylidene)-α-D-glucoheptonic γ-lactone

: 270902-66-4
(4S,4aR,7R,7aR)-7-methoxy-2,2-dimethyl-6-oxotetrahydro-4H-furo[3,2-d][1,3]dioxine-4-carbaldehyde

Guidance literature:: Multi-step reaction with 3 steps

1: 82 percent / Ag₂O; H₂O / CH₂Cl₂ / 18 h / 15 - 30 °C

2: 67.6 percent / acetic acid; H₂O / 20 °C

3: 85 percent / NaIO₄ / methanol; H₂O / 0.67 h / 8 °C

With sodium periodate; water; silver(l) oxide; In methanol; dichloromethane; water; acetic acid;
DOI:10.1021/jo0017133

Reference yield:

: 136289-11-7
(4R,4aS,7R,7aR)-4-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-7-methoxy-2,2-dimethyl-tetrahydro-6H-furo[3,2-d][1,3]dioxin-6-one

: 270902-66-4
(4S,4aR,7R,7aR)-7-methoxy-2,2-dimethyl-6-oxotetrahydro-4H-furo[3,2-d][1,3]dioxine-4-carbaldehyde

Guidance literature:: Multi-step reaction with 2 steps

1: 67.6 percent / acetic acid; H₂O / 20 °C

2: 85 percent / NaIO₄ / methanol; H₂O / 0.67 h / 8 °C

With sodium periodate; In methanol; water; acetic acid;
DOI:10.1021/jo0017133