(5Z)-1-tert-Butyldiphenylsilyloxy-9-(phenylthiomethylene)undeca-5,10-diene

Base Information

Chemical Name:(5Z)-1-tert-Butyldiphenylsilyloxy-9-(phenylthiomethylene)undeca-5,10-diene
CAS No.:137032-17-8
Molecular Formula:C₃₄H₄₂OSSi
Molecular Weight:526.858
Hs Code.:

Synonyms:(5Z)-1-tert-Butyldiphenylsilyloxy-9-(phenylthiomethylene)undeca-5,10-diene

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Chemical Property of (5Z)-1-tert-Butyldiphenylsilyloxy-9-(phenylthiomethylene)undeca-5,10-diene

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Technology Process of (5Z)-1-tert-Butyldiphenylsilyloxy-9-(phenylthiomethylene)undeca-5,10-diene

There total 8 articles about (5Z)-1-tert-Butyldiphenylsilyloxy-9-(phenylthiomethylene)undeca-5,10-diene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 928-90-5
5-hexyl-1-ol

: 137032-17-8
(5Z)-1-tert-Butyldiphenylsilyloxy-9-(phenylthiomethylene)undeca-5,10-diene

Guidance literature:: Multi-step reaction with 7 steps

1: imidazole / dimethylformamide / Ambient temperature; overnight

2: 1.) BuLi, 1,3-dimethyl-imidazolidin-2-one (DMEU) / 1.) THF, hexane, 0 deg C, 15 min; 2.) THF, r.t., 48 h

3: NaBH₄, H₂, EDA*H₂O, Ni(OAc)2*4H₂O / ethanol / 2 h / Ambient temperature

4: 1.) NCS; 2.) CuO, CuCl₂*2H₂O / 1.) CCl₄, 0 deg C to r.t., overnight; 2.) H₂O, acetone, reflux, 45 min

5: 77 percent / tetrahydrofuran / 0.25 h / -78 °C

6: 65 percent / PDC / CH₂Cl₂ / 10 h / Ambient temperature

7: 1.) BuLi / 1.) THF, hexane, -8 deg C, 0.5 h; 2.) THF, -78 deg C, 20 min

With 1H-imidazole; 1,3-dimethyl-2-imidazolidinone; sodium tetrahydroborate; N-chloro-succinimide; dipyridinium dichromate; n-butyllithium; EDA*H₂O; hydrogen; nickel diacetate; copper(II) oxide; In tetrahydrofuran; ethanol; dichloromethane; N,N-dimethyl-formamide;

Reference yield:

: 128217-23-2
1-(tert-butyldiphenylsilyloxy)-5-hexyne

: 137032-17-8
(5Z)-1-tert-Butyldiphenylsilyloxy-9-(phenylthiomethylene)undeca-5,10-diene

Guidance literature:: Multi-step reaction with 6 steps

1: 1.) BuLi, 1,3-dimethyl-imidazolidin-2-one (DMEU) / 1.) THF, hexane, 0 deg C, 15 min; 2.) THF, r.t., 48 h

2: NaBH₄, H₂, EDA*H₂O, Ni(OAc)2*4H₂O / ethanol / 2 h / Ambient temperature

3: 1.) NCS; 2.) CuO, CuCl₂*2H₂O / 1.) CCl₄, 0 deg C to r.t., overnight; 2.) H₂O, acetone, reflux, 45 min

4: 77 percent / tetrahydrofuran / 0.25 h / -78 °C

5: 65 percent / PDC / CH₂Cl₂ / 10 h / Ambient temperature

6: 1.) BuLi / 1.) THF, hexane, -8 deg C, 0.5 h; 2.) THF, -78 deg C, 20 min

With 1,3-dimethyl-2-imidazolidinone; sodium tetrahydroborate; N-chloro-succinimide; dipyridinium dichromate; n-butyllithium; EDA*H₂O; hydrogen; nickel diacetate; copper(II) oxide; In tetrahydrofuran; ethanol; dichloromethane;

Reference yield:

: 137032-15-6
9-tert-Butyldiphenylsilyloxy-(Z)-non-4-en-1-al

: 137032-17-8
(5Z)-1-tert-Butyldiphenylsilyloxy-9-(phenylthiomethylene)undeca-5,10-diene

Guidance literature:: Multi-step reaction with 3 steps

1: 77 percent / tetrahydrofuran / 0.25 h / -78 °C

2: 65 percent / PDC / CH₂Cl₂ / 10 h / Ambient temperature

3: 1.) BuLi / 1.) THF, hexane, -8 deg C, 0.5 h; 2.) THF, -78 deg C, 20 min

With dipyridinium dichromate; n-butyllithium; In tetrahydrofuran; dichloromethane;