1-bromo-(-)-menthyl propiolate

Base Information

Chemical Name:1-bromo-(-)-menthyl propiolate
CAS No.:1346267-01-3
Molecular Formula:C₁₃H₁₉BrO₂
Molecular Weight:287.197
Hs Code.:

Synonyms:1-bromo-(-)-menthyl propiolate

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Chemical Property of 1-bromo-(-)-menthyl propiolate

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Technology Process of 1-bromo-(-)-menthyl propiolate

There total 1 articles about 1-bromo-(-)-menthyl propiolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 65018-52-2
(1R,2S,5R)-2-isopropyl-5-methylcyclohexyl propiolate

: 1346267-01-3
1-bromo-(-)-menthyl propiolate

Guidance literature:: With N-Bromosuccinimide; silver nitrate; In acetone; at 20 ℃; for 1.33333h;
DOI:10.1016/j.ica.2011.02.074

Reference yield: 99.0%

: 14221-01-3
tetrakis(triphenylphosphine) palladium⁽⁰⁾

: 1346267-01-3
1-bromo-(-)-menthyl propiolate

: trans-bromo(3-((-)-menthoxy)-3-oxy-1-propynyl)bis(triphenylphosphine)palladium(II)

Guidance literature:: In dichloromethane; byproducts: PPh3; under inert atmosphere; suspn. of Pd(PPh3)4 in CH2Cl2 treated with ligand at ambient temp.; stirred for 30 min; solvent removed in vac.; purified by column chromy. (silica gel, petroleum ether-CH2Cl2); solvent removed; elem. anal.;
DOI:10.1021/om200862m