tetrakis[bis(phenylthio)methyl]silane

Base Information

Chemical Name:tetrakis[bis(phenylthio)methyl]silane
CAS No.:1266779-33-2
Molecular Formula:C₅₂H₄₄S₈Si
Molecular Weight:953.535
Hs Code.:

Synonyms:tetrakis[bis(phenylthio)methyl]silane

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Chemical Property of tetrakis[bis(phenylthio)methyl]silane

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Technology Process of tetrakis[bis(phenylthio)methyl]silane

There total 1 articles about tetrakis[bis(phenylthio)methyl]silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 3561-67-9
bis(phenylthio)methane

: 1266779-33-2
tetrakis[bis(phenylthio)methyl]silane

Guidance literature:: bis(phenylthio)methane; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h;

With tetrachlorosilane; In tetrahydrofuran; hexane; at -78 - 20 ℃;
DOI:10.1016/j.jorganchem.2010.09.080

Reference yield: 73.0%

: 185991-38-2
titanocene(II) triethylphosphite complex

: 1266779-33-2
tetrakis[bis(phenylthio)methyl]silane

: 2,2,6,6-tetrakis(η5-cyclopentadienyl)-1,3,5,7-tetrakis(phenylthio)-4-sila-2,6-dititanaspiro[3.3]heptane

Guidance literature:: In tetrahydrofuran; byproducts: Cp2Ti(SPh)2; THF soln. of Si(CH(SPh)2)4 (1.0 mmol) added at 25 °C to THF soln.of Cp2Ti(P(OEt3))2 in situ prepd. from Mg (4.4 mmol), mol. sieves, Cp2T iCl2 (4.0 mmol) and P(OEt)3 (8.0 mmol), stirred at 25 °C for 2 h; filtered, chromd. (alumina gel, THF) under N2, evaporated under vac.; elem. anal.;
DOI:10.1016/j.jorganchem.2010.09.080

Reference yield: 68.0%

: 1266779-33-2
tetrakis[bis(phenylthio)methyl]silane

: 18762-89-5
tetrakis[(phenylthio)methyl]silane

Guidance literature:: tetrakis[bis(phenylthio)methyl]silane; With bis(cyclopentadienyl)titanium dichloride; magnesium; triethyl phosphite; In tetrahydrofuran; at 25 ℃; for 5h; under 2 - 3 Torr; Inert atmosphere; Molecular sieve;

With acetic acid; In tetrahydrofuran; water; for 10h; Reflux;
DOI:10.1016/j.jorganchem.2010.09.080