mesitylphosphilidene

Base Information

• Chemical Name: mesitylphosphilidene
• CAS No.: 157372-53-7
• Molecular Formula: C₉H₁₁P
• Molecular Weight: 150.16
• Mol file: 157372-53-7.mol

Synonyms:mesitylphosphilidene

Chemical Property of mesitylphosphilidene

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of mesitylphosphilidene

There total 3 articles about mesitylphosphilidene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

mesitylphosphine (68357-98-2) → mesitylphosphilidene (157372-53-7)

Guidance literature:

Multi-step reaction with 2 steps

1: Inert atmosphere; Schlenk technique

2: methyl cyclohexane / 0.83 h / Inert atmosphere; Sealed tube; UV-irradiation

In methyl cyclohexane;

DOI:10.1002/anie.201703629

Reference yield:

1-mesitylphosphirane (100073-28-7) → mesitylphosphilidene (157372-53-7)

Guidance literature:

In various solvent(s); at -268.15 ℃; for 1h; Flash photolysis;

DOI:10.1002/anie.200462862

Reference yield:

trans-(+/-)-2,3-dimethyl-1-mesitylphosphirane → mesitylphosphilidene (157372-53-7)

Guidance literature:

In cyclohexane; at -196.15 ℃; Flash photolysis;

DOI:10.1002/anie.200462862

upstream raw materials:

1-mesitylphosphirane

mesitylphosphine

Downstream raw materials:

2,4-dimethyl-2,3-pentadiene

Refernces

• 1、 Akimov, Alexander V.,Ganushevich, Yulia S.,Korchagin, Denis V.,Miluykov, Vasili A.,Misochko, Eugenii Y.. "The EPR Spectrum of Triplet Mesitylphosphinidene: Reassignment and New Assignment". supporting information. p. 7944 - 7947. Retrieved 2017/06/27.