tert-Butyl-[(1S,5S)-5-(1-ethoxy-2-iodo-ethoxy)-2-methyl-6-methylene-cyclohex-2-enylmethoxy]-diphenyl-silane

Base Information

Chemical Name:tert-Butyl-[(1S,5S)-5-(1-ethoxy-2-iodo-ethoxy)-2-methyl-6-methylene-cyclohex-2-enylmethoxy]-diphenyl-silane
CAS No.:880090-15-3
Molecular Formula:C₂₉H₃₉IO₃Si
Molecular Weight:590.617
Hs Code.:

Synonyms:tert-Butyl-[(1S,5S)-5-(1-ethoxy-2-iodo-ethoxy)-2-methyl-6-methylene-cyclohex-2-enylmethoxy]-diphenyl-silane

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Chemical Property of tert-Butyl-[(1S,5S)-5-(1-ethoxy-2-iodo-ethoxy)-2-methyl-6-methylene-cyclohex-2-enylmethoxy]-diphenyl-silane

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Technology Process of tert-Butyl-[(1S,5S)-5-(1-ethoxy-2-iodo-ethoxy)-2-methyl-6-methylene-cyclohex-2-enylmethoxy]-diphenyl-silane

There total 6 articles about tert-Butyl-[(1S,5S)-5-(1-ethoxy-2-iodo-ethoxy)-2-methyl-6-methylene-cyclohex-2-enylmethoxy]-diphenyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 880090-14-2
(1S,5S)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-4-methyl-6-methylene-cyclohex-3-enol

: 109-92-2,25104-37-4
ethyl vinyl ether

: 880090-15-3
tert-Butyl-[(1S,5S)-5-(1-ethoxy-2-iodo-ethoxy)-2-methyl-6-methylene-cyclohex-2-enylmethoxy]-diphenyl-silane

Guidance literature:: With N-iodo-succinimide; In dichloromethane; at -20 - 0 ℃;
DOI:10.1016/j.tetlet.2005.12.099

Reference yield:

: 880090-04-0
2,6-dimethyl-cyclohexa-2,5-dienecarboxylic acid methyl ester

: 880090-15-3
tert-Butyl-[(1S,5S)-5-(1-ethoxy-2-iodo-ethoxy)-2-methyl-6-methylene-cyclohex-2-enylmethoxy]-diphenyl-silane

Guidance literature:: Multi-step reaction with 5 steps

1: 97 percent / LAH / tetrahydrofuran / 0 °C

2: 98 percent / imidazole / CH₂Cl₂ / 0 - 20 °C

3: chiral ketone; Oxone; (MeO)2CH₂ / acetonitrile; H₂O / 3.5 h / -10 °C / pH 10.5

4: 97 percent / Et₂AlTMP / toluene / 0 °C

5: 80 percent / NIS / CH₂Cl₂ / -20 - 0 °C

With 1H-imidazole; Oxone; N-iodo-succinimide; lithium aluminium tetrahydride; Dimethoxymethane; Chiral ketone; In tetrahydrofuran; dichloromethane; water; toluene; acetonitrile;
DOI:10.1016/j.tetlet.2005.12.099

Reference yield:

: 31673-42-4
2,6-dimethylcyclohexa-2,5-diene-1-carboxylic acid

: 880090-15-3
tert-Butyl-[(1S,5S)-5-(1-ethoxy-2-iodo-ethoxy)-2-methyl-6-methylene-cyclohex-2-enylmethoxy]-diphenyl-silane

Guidance literature:: Multi-step reaction with 6 steps

1: 100 percent / diethyl ether / 0 °C

2: 97 percent / LAH / tetrahydrofuran / 0 °C

3: 98 percent / imidazole / CH₂Cl₂ / 0 - 20 °C

4: chiral ketone; Oxone; (MeO)2CH₂ / acetonitrile; H₂O / 3.5 h / -10 °C / pH 10.5

5: 97 percent / Et₂AlTMP / toluene / 0 °C

6: 80 percent / NIS / CH₂Cl₂ / -20 - 0 °C

With 1H-imidazole; Oxone; N-iodo-succinimide; lithium aluminium tetrahydride; Dimethoxymethane; Chiral ketone; In tetrahydrofuran; diethyl ether; dichloromethane; water; toluene; acetonitrile;
DOI:10.1016/j.tetlet.2005.12.099