2,5-dimethyl-4-[diphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silyloxy]-1-hexen

Base Information

• Chemical Name: 2,5-dimethyl-4-[diphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silyloxy]-1-hexen
• CAS No.: 1158817-44-7
• Molecular Formula: C₂₆H₃₇BO₃Si
• Molecular Weight: 436.474
• Mol file: 1158817-44-7.mol

Synonyms:2,5-dimethyl-4-[diphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silyloxy]-1-hexen

Chemical Property of 2,5-dimethyl-4-[diphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silyloxy]-1-hexen

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,5-dimethyl-4-[diphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silyloxy]-1-hexen

There total 1 articles about 2,5-dimethyl-4-[diphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silyloxy]-1-hexen which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-(chlorodiphenylsilyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (915225-49-9) + 2,5-dimethyl-5-hexen-3-ol (19550-91-5) → 2,5-dimethyl-4-[diphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silyloxy]-1-hexen (1158817-44-7)

Guidance literature:

With pyridine; In dichloromethane; at 0 - 20 ℃;

DOI:10.1002/anie.200805406

Reference yield: 72.0%

2,5-dimethyl-4-[diphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silyloxy]-1-hexen (1158817-44-7) → (E)-2,5-dimethyl-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-4-(diphenylsilyloxy)hex-1-ene (1158817-67-4)

Guidance literature:

With bis[(E,E)-1,5-diphenyl-3-oxopenta-1,4-diene]platinum(II); triphenylphosphine; In toluene; at 110 ℃; for 6h; diastereoselective reaction;

DOI:10.1002/anie.200805406

upstream raw materials:

2-(chlorodiphenylsilyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

2,5-dimethyl-5-hexen-3-ol

Downstream raw materials:

(E)-2,5-dimethyl-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-4-(diphenylsilyloxy)hex-1-ene