2,5-bis-[4-(6-bromo-hexyloxy)-benzoyloxy]-terephthalic acid dibut-3-enyl ester

Base Information

• Chemical Name: 2,5-bis-[4-(6-bromo-hexyloxy)-benzoyloxy]-terephthalic acid dibut-3-enyl ester
• CAS No.: 1192023-22-5
• Molecular Formula: C₄₂H₄₈Br₂O₁₀
• Molecular Weight: 872.645
• Mol file: 1192023-22-5.mol

Synonyms:2,5-bis-[4-(6-bromo-hexyloxy)-benzoyloxy]-terephthalic acid dibut-3-enyl ester

Chemical Property of 2,5-bis-[4-(6-bromo-hexyloxy)-benzoyloxy]-terephthalic acid dibut-3-enyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,5-bis-[4-(6-bromo-hexyloxy)-benzoyloxy]-terephthalic acid dibut-3-enyl ester

There total 1 articles about 2,5-bis-[4-(6-bromo-hexyloxy)-benzoyloxy]-terephthalic acid dibut-3-enyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-(6-bromohexoxy)benzoyl chloride + 2,5-dihydroxy-terephthalic acid dibut-3-enyl ester (1192023-21-4) → 2,5-bis-[4-(6-bromo-hexyloxy)-benzoyloxy]-terephthalic acid dibut-3-enyl ester (1192023-22-5)

Guidance literature:

With triethylamine; In dichloromethane; at 20 ℃; for 1h; Inert atmosphere;

DOI:10.1021/ja905363f

Reference yield: 60.7%

2,5-bis-[4-(6-bromo-hexyloxy)-benzoyloxy]-terephthalic acid dibut-3-enyl ester (1192023-22-5) → 2,5-bis-[4-(6-mercapto-hexyloxy)-benzoyloxy]-terephthalic acid dibut-3-enyl ester (1192023-23-6)

Guidance literature:

With hexamethyldisilathiane; tetrabutyl ammonium fluoride; In tetrahydrofuran; at -10 ℃; for 0.166667h; Inert atmosphere;

DOI:10.1021/ja905363f

upstream raw materials:

2,5-dihydroxy-terephthalic acid dibut-3-enyl ester

Downstream raw materials:

2,5-bis-[4-(6-mercapto-hexyloxy)-benzoyloxy]-terephthalic acid dibut-3-enyl ester