Copper(II) nitrate trihydrate

Base Information

• Chemical Name: Copper(II) nitrate trihydrate
• CAS No.: 10031-43-3
• Molecular Formula: Cu(NO3)2^.3(H2O)
• Molecular Weight: 241.62
• Hs Code.: 28342930
• European Community (EC) Number: 600-060-3
• UNII: 066PG1506T
• DSSTox Substance ID: DTXSID0051445
• Wikipedia: Copper(II) nitrate trihydrate
• Wikidata: Q27236183
• Mol file: 10031-43-3.mol

Synonyms:Copper(II) nitrate trihydrate;10031-43-3;Cupric nitrate trihydrate;Copper nitrate trihydrate;Gerhardite;Copper dinitrate trihydrate;copper;dinitrate;trihydrate;Copper(2+) nitrate trihydrate;Nitric acid, copper(2+) salt, trihydrate;UNII-066PG1506T;COPPER(II) NITRATE, TRIHYDRATE (1:2:3);Nitric acid, copper(2+) salt, hydrate (2:1:3);MFCD00149671;066PG1506T;Nitrate cuivrique trihydrat;copper(II)nitrate trihydrate;N2O6.Cu.3H2O;Copper( cento) nitrate hydrate;N2-O6.Cu.3H2-O;DTXSID0051445;SXTLQDJHRPXDSB-UHFFFAOYSA-N;MFCD02253001;AKOS015903801;CUPRIC NITRATE TRIHYDRATE [MI];Nitric acid, copper(2) salt, trihydrate;Q27236183

Chemical Property of Copper(II) nitrate trihydrate

Chemical Property:

• Appearance/Colour: Hygroscopic blue crystal
• Melting Point: 114 °C
• Boiling Point: 83 °C at 760 mmHg
• PSA: 165.45000
• Density: 2,32 g/cm3
• LogP: 0.37280
• Storage Temp.: 0-6°C
• Solubility.: 2670g/l
• Water Solubility.: soluble
• Hydrogen Bond Donor Count: 3
• Hydrogen Bond Acceptor Count: 9
• Rotatable Bond Count: 0
• Exact Mass: 240.936927
• Heavy Atom Count: 12
• Complexity: 18.8

Purity/Quality:

99.9% ^*data from raw suppliers

Copper(II) nitrate trihydrate (99.999%-Cu) PURATREM ^*data from reagent suppliers

Safty Information:

• Pictogram(s): O,C,Xn
• Hazard Codes: O,C,Xn,N
• Statements: 8-22-34-36/38-50/53-41-38
• Safety Statements: 17-26-36/37/39-45-37/39-61-60-39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Metals, Inorganic Compounds
• Canonical SMILES: [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].O.O.O.[Cu+2]
• Description: Cupric nitrate is the cupric salt of nitrate. Cupric nitrate has various applications: a major application is its conversion to copper oxide, a powerful catalyst organic chemistry. It can also be used in textiles and polishing agents of other metals. It can also be used to demonstrate chemical voltaic cell reactions in schools. During organic synthesis, it can be combined with acetic anhydride to be used as an effective reagent for nitration of aromatic compounds. Its hydrate form can catalyze oxidative coupling of 2, 6-dimethylphenol to produce a polymer which is an important engineering material. Its tri-hydrate form can catalyze the solvent-free synthesis of 3-aminopropenones and 3-aminopropenoates. Its pentahydrate form may be used in the preparation of novel coordination polymers. It also has applications in medicine, as an insecticide, in chemical analysis, in making light sensitive papers.
• Uses: Analytical Reagent Copper(II) nitrate trihydrate may be used in the preparation of the following mononuclear copper(II) complexes (phen = 1,10-phenanthroline, dpq = dipyrido[3,2-d:2′,3′-f]quinoxaline and dppz = dipyrido[3,2-a:2′,3′-c]phenazine):[Cu(dpq)(NO3)2][Cu(dpq)(NO3)(H2O)2](NO3)[Cu(dpq)(NO3)2(H2O)2]·2H2O[Cu(dppz)(NO3)2(H2O)]·H2O

Refernces

Microwave assisted one pot three component synthesis of propargylamine, tetra substituted propargylamine and pyrrolo[1,2-: A] quinolines using CuNPs@ZnO-PTh as a heterogeneous catalyst

10.1039/c8nj00410b

The research focuses on the development and investigation of the catalytic activity of copper nanoparticles (CuNPs) supported on a Zinc oxide-polythiophene (ZnO-PTh) nanocomposite, denoted as CuNPs@ZnO-PTh. The purpose of this study was to create an efficient, cost-effective, and environmentally benign catalyst for the synthesis of propargylamine, tetra-substituted propargylamine, and pyrrolo[1,2-a]quinolines through A3 and KA2 coupling reactions. The researchers used a variety of chemicals in the synthesis process, including zinc chloride, sodium hydroxide, sodium dodecyl sulfate, thiophene, ferric chloride, copper nitrate trihydrate, and hydrazine hydrate. The conclusions drawn from the study highlight the high catalytic performance of the CuNPs@ZnO-PTh catalyst, which was attributed to its high surface area and the synergistic effect of both CuNPs and ZnO-PTh. The catalyst demonstrated excellent activity, selectivity, and recyclability, with the reactions yielding high product yields (up to 98%) in ethylene glycol, a green and biodegradable solvent, under microwave irradiation. The study concludes that this protocol is more efficient and sustainable compared to existing commercial methods.

Two polyoxoniobates-based ionic crystals as Lewis base catalysts for cyanosilylation

10.1016/j.inoche.2019.107666

The research focuses on the synthesis and catalytic application of two transition-metal containing heteropolyniobates, H[Ni(en)3]5[VNb12O40(VO)2]?15H2O (1) and H3[Cu(en)2]4[VNb12O40(VO)2]?13H2O (2). These compounds were synthesized using ethylene glycol and water as a mixed solvent, with ethylenediamine (en), nickel(II) chloride hexahydrate (NiCl2·6H2O), copper(II) nitrate trihydrate (Cu(NO3)2·3H2O), potassium hexaniobate (K7HNb6O19·13H2O), and sodium vanadate (NaVO3) playing crucial roles in the solvothermal synthesis process. The resulting compounds exhibited remarkable catalytic performance for the cyanosilylation of various aldehydes and ketones, yielding cyanohydrin trimethylsilyl ethers with high efficiency. The study highlights the importance of the synergistic effect between the polyoxoniobate anions and transition-metal chelates in enhancing the catalytic activity, with catalyst 1 achieving a turnover frequency (TOF) of 515.5 h-1 for benzaldehyde cyanosilylation at a loading of 0.1 mol%.