(-)-<(1S,2R,4S)-2-acetoxy-4-<(benzyloxy)methyl>cyclopentyl>methyl benzoate

Base Information

Chemical Name:(-)-<(1S,2R,4S)-2-acetoxy-4-<(benzyloxy)methyl>cyclopentyl>methyl benzoate
CAS No.:120963-38-4
Molecular Formula:C₂₃H₂₆O₅
Molecular Weight:382.456
Hs Code.:

Synonyms:(-)-<(1S,2R,4S)-2-acetoxy-4-<(benzyloxy)methyl>cyclopentyl>methyl benzoate

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Chemical Property of (-)-<(1S,2R,4S)-2-acetoxy-4-<(benzyloxy)methyl>cyclopentyl>methyl benzoate

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Technology Process of (-)-<(1S,2R,4S)-2-acetoxy-4-<(benzyloxy)methyl>cyclopentyl>methyl benzoate

There total 5 articles about (-)-<(1S,2R,4S)-2-acetoxy-4-<(benzyloxy)methyl>cyclopentyl>methyl benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: 3396-11-0
cesium acetate

: 120963-37-3
(+)-(1S,2S,4S)-2-<(benzoyloxy)methyl>-4-<(benzyloxy)methyl>cyclopentyl methanesulfonate

: 120905-31-9
Benzoic acid (R)-4-benzyloxymethyl-cyclopent-1-enylmethyl ester

: 120963-38-4
(-)-<(1S,2R,4S)-2-acetoxy-4-<(benzyloxy)methyl>cyclopentyl>methyl benzoate

Guidance literature:: In dimethyl sulfoxide; at 40 - 45 ℃;
DOI:10.1021/jm00128a029

Reference yield:

: 120963-35-1
(+)-(1S,2S,4S)-4-<(benzyloxy)methyl>-2-hydroxycyclopentanemethanol

: 120963-38-4
(-)-<(1S,2R,4S)-2-acetoxy-4-<(benzyloxy)methyl>cyclopentyl>methyl benzoate

Guidance literature:: Multi-step reaction with 3 steps

1: 99 percent / pyridine / CH₂Cl₂ / 0.17 h

2: 90 percent / Et₃N / CH₂Cl₂ / 3 h / Ambient temperature

3: 58 percent / dimethylsulfoxide / 40 - 45 °C

With pyridine; triethylamine; In dichloromethane; dimethyl sulfoxide;
DOI:10.1021/jm00128a029

Reference yield:

: (+)-(1S,6S,8S)-3-phenyl-2,4-dioxabicyclo<4.3.0>nonane-8-methanol

: 120963-38-4
(-)-<(1S,2R,4S)-2-acetoxy-4-<(benzyloxy)methyl>cyclopentyl>methyl benzoate

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) KH / 1.) THF, room temperature, 20 min, 2.) 12 h

2: 98 percent / conc. H₂SO₄ / H₂O / 0.17 h / Heating

3: 99 percent / pyridine / CH₂Cl₂ / 0.17 h

4: 90 percent / Et₃N / CH₂Cl₂ / 3 h / Ambient temperature

5: 58 percent / dimethylsulfoxide / 40 - 45 °C

With pyridine; sulfuric acid; potassium hydride; triethylamine; In dichloromethane; water; dimethyl sulfoxide;
DOI:10.1021/jm00128a029