(bicyclo{2.2.1}hepta-2,5-diene){R-(R(),R())-1,2-phenylenebis(methylphenylarsine)}rhodium(I)

Base Information

Chemical Name:(bicyclo{2.2.1}hepta-2,5-diene){R-(R(*),R(*))-1,2-phenylenebis(methylphenylarsine)}rhodium(I)
CAS No.:100945-99-1
Molecular Formula:C₂₇H₂₈As₂Rh*F₆P
Molecular Weight:750.232
Hs Code.:

Synonyms:(bicyclo{2.2.1}hepta-2,5-diene){R-(R(*),R(*))-1,2-phenylenebis(methylphenylarsine)}rhodium(I)

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Chemical Property of (bicyclo{2.2.1}hepta-2,5-diene){R-(R(*),R(*))-1,2-phenylenebis(methylphenylarsine)}rhodium(I)

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Technology Process of (bicyclo{2.2.1}hepta-2,5-diene){R-(R(*),R(*))-1,2-phenylenebis(methylphenylarsine)}rhodium(I)

There total 1 articles about (bicyclo{2.2.1}hepta-2,5-diene){R-(R(*),R(*))-1,2-phenylenebis(methylphenylarsine)}rhodium(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: ammonium hexafluorophosphate

: 12257-42-0
[(norbornadiene)rhodium(I)chloride]2

: 52120-04-4,55289-90-2,55289-91-3,57341-01-2,57375-33-4
o-Phenylen-bis-(methylphenylarsin)

: 100945-99-1
(bicyclo{2.2.1}hepta-2,5-diene){R-(R(*),R(*))-1,2-phenylenebis(methylphenylarsine)}rhodium(I)

Guidance literature:: With silver nitrate; In methanol; water; byproducts: AgCl; stirring of Rh complex and AgNO3 (molar ratio 1:2) in MeOH under Ar for30 min, addn. of ligand, filtn., of AgCl, treating with aq. NH4PF6; filtn., washing with water, drying, recrystn. from acetone and Et2O, elem. anal.;
DOI:10.1021/om00136a029