C₅₂H₈₂O₁₇Si

Base Information

Chemical Name:C₅₂H₈₂O₁₇Si
CAS No.:204448-73-7
Molecular Formula:C₅₂H₈₂O₁₇Si
Molecular Weight:1007.3
Hs Code.:

C<sub>52</sub>H<sub>82</sub>O<sub>17</sub>Si

Synonyms:C₅₂H₈₂O₁₇Si

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Chemical Property of C₅₂H₈₂O₁₇Si

Chemical Property:

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Technology Process of C₅₂H₈₂O₁₇Si

There total 45 articles about C₅₂H₈₂O₁₇Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₅₂H₈₂O₁₆Si

: 204448-73-7
C₅₂H₈₂O₁₇Si

Guidance literature:: With sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; In tert-butyl alcohol; Yield given;
DOI:10.1002/(sici)1521-3773(19980202)37:1/2<187::aid-anie187>3.0.co;2-d

Reference yield:

: 111322-01-1,119239-98-4,91285-62-0
(R)-1-benzyloxy-hex-5-en-3-ol

: 204448-73-7
C₅₂H₈₂O₁₇Si

Guidance literature:: Multi-step reaction with 27 steps

2: 92 percent / imidazole / CH₂Cl₂

3: 97 percent / BuLi, DMPU / tetrahydrofuran / 1.) -20 deg C; -78 deg C, 2.) -20 deg C

4: 87 percent / imidazole / CH₂Cl₂

5: 59 percent / tert-BuONa, BuLi / pentane / 1.) -78 deg C, 2.) -78 to -20 deg C

6: 80 percent / PPTS, MeOH

7: 93 percent / NaH, p-toluenesulfonyl imidazole / tetrahydrofuran / 1.) 0 deg C, 2.) 0 deg C

8: 1.) tert-BuLi, 2.) lithium 2-thienylcyanocuprate / 1.) THF, -78 deg C, 2.) -78 to 0 deg C

9: TBAF / 0 °C

10: CaCO₃, N-iodosuccinimide / acetonitrile / 0 °C

11: PPTS / acetonitrile

12: Li, NH₃ / tetrahydrofuran / -78 °C

13: 93 percent / pyridine / CH₂Cl₂

14: 87 percent / PPTS, MeOH / 50 °C

15: 94 percent / Et₃N, DMAP / CH₂Cl₂

16: 96 percent / pyridine, DMAP

17: 95 percent / hydrogen fluoride pyridine complex / acetonitrile

18: 91 percent / Dess-Martin periodinane / CH₂Cl₂

19: 86 percent / NiCl₂, CrCl₂, (-)-bispyridinyl ligand / tetrahydrofuran

20: 83 percent / Dess-Martin periodinane, pyridine / CH₂Cl₂

21: H₂O, PPTS / acetone

22: Triton-B / methanol; methyl acetate / 0 °C

23: hydrogene fluoride pyridine complex / acetonitrile

24: 79 percent / 2,6-lutidine / -78 °C

25: 82 percent / hydrogene fluoride pyridine complex, pyridine / tetrahydrofuran

26: N-methylmorpholine N-oxide, tetrapropylammonium perruthenate, molecular sieves 4 Angstroem / CH₂Cl₂

27: NaClO₂, NaH₂PO₄, 2-methyl-2-butene / 2-methyl-propan-2-ol

With pyridine; 1H-imidazole; 2,6-dimethylpyridine; chromium dichloride; methanol; dmap; 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; sodium chlorite; sodium dihydrogenphosphate; N-iodo-succinimide; n-butyllithium; tetrapropylammonium perruthennate; 2-methyl-but-2-ene; (-)-bispyridinyl ligand; 4 A molecular sieve; tetrabutyl ammonium fluoride; ammonia; water; tert.-butyl lithium; pyridinium p-toluenesulfonate; N-benzyl-trimethylammonium hydroxide; lithium; sodium hydride; Dess-Martin periodane; pyridine hydrogenfluoride; 4-methylmorpholine N-oxide; thien-2-yl(cyano)copper lithium; triethylamine; N-tosylimidazole; calcium carbonate; nickel dichloride; sodium t-butanolate; In tetrahydrofuran; methanol; dichloromethane; acetic acid methyl ester; acetone; acetonitrile; tert-butyl alcohol; pentane;
DOI:10.1002/(sici)1521-3773(19980202)37:1/2<187::aid-anie187>3.0.co;2-d

Reference yield:

: (2R,4S)-5-Iodo-4-methyl-pentane-1,2,4-triol

: 204448-73-7
C₅₂H₈₂O₁₇Si

Guidance literature:: Multi-step reaction with 26 steps

1: 96 percent / PPTS / CH₂Cl₂

2: 94 percent / K₂CO₃

3: 87 percent / imidazole

4: 59 percent / tert-BuONa, BuLi / pentane / 1.) -78 deg C, 2.) -78 to -20 deg C

5: 80 percent / PPTS, MeOH

6: 93 percent / NaH, p-toluenesulfonyl imidazole / tetrahydrofuran / 1.) 0 deg C, 2.) 0 deg C

7: 1.) tert-BuLi, 2.) lithium 2-thienylcyanocuprate / 1.) THF, -78 deg C, 2.) -78 to 0 deg C

8: TBAF / 0 °C

9: CaCO₃, N-iodosuccinimide / acetonitrile / 0 °C

10: PPTS / acetonitrile

11: Li, NH₃ / tetrahydrofuran / -78 °C

12: 93 percent / pyridine / CH₂Cl₂

13: 87 percent / PPTS, MeOH / 50 °C

14: 94 percent / Et₃N, DMAP / CH₂Cl₂

15: 96 percent / pyridine, DMAP

16: 95 percent / hydrogen fluoride pyridine complex / acetonitrile

17: 91 percent / Dess-Martin periodinane / CH₂Cl₂

18: 86 percent / NiCl₂, CrCl₂, (-)-bispyridinyl ligand / tetrahydrofuran

19: 83 percent / Dess-Martin periodinane, pyridine / CH₂Cl₂

20: H₂O, PPTS / acetone

21: Triton-B / methanol; methyl acetate / 0 °C

22: hydrogene fluoride pyridine complex / acetonitrile

23: 79 percent / 2,6-lutidine / -78 °C

24: 82 percent / hydrogene fluoride pyridine complex, pyridine / tetrahydrofuran

25: N-methylmorpholine N-oxide, tetrapropylammonium perruthenate, molecular sieves 4 Angstroem / CH₂Cl₂

26: NaClO₂, NaH₂PO₄, 2-methyl-2-butene / 2-methyl-propan-2-ol

With pyridine; 1H-imidazole; 2,6-dimethylpyridine; chromium dichloride; methanol; dmap; sodium chlorite; sodium dihydrogenphosphate; N-iodo-succinimide; n-butyllithium; tetrapropylammonium perruthennate; 2-methyl-but-2-ene; (-)-bispyridinyl ligand; 4 A molecular sieve; tetrabutyl ammonium fluoride; ammonia; water; tert.-butyl lithium; pyridinium p-toluenesulfonate; N-benzyl-trimethylammonium hydroxide; lithium; sodium hydride; potassium carbonate; Dess-Martin periodane; pyridine hydrogenfluoride; 4-methylmorpholine N-oxide; thien-2-yl(cyano)copper lithium; triethylamine; N-tosylimidazole; calcium carbonate; nickel dichloride; sodium t-butanolate; In tetrahydrofuran; methanol; dichloromethane; acetic acid methyl ester; acetone; acetonitrile; tert-butyl alcohol; pentane;
DOI:10.1002/(sici)1521-3773(19980202)37:1/2<187::aid-anie187>3.0.co;2-d