Technology Process of C47H49BI2N2Si
There total 3 articles about C47H49BI2N2Si which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
1-ethynyl-4-iodobenzene;
With
ethylmagnesium bromide;
In
tetrahydrofuran;
at 60 ℃;
for 2h;
Schlenk technique;
Si(CH2CH3)3C2C6H4C(C4N(CH3)2CH2CH3)2BF2;
In
tetrahydrofuran;
at 60 ℃;
DOI:10.1021/ja4049306
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: dichloromethane / 20 °C
2.1: bis-triphenylphosphine-palladium(II) chloride; diisopropylamine / tetrahydrofuran / 0.5 h / Schlenk technique; Inert atmosphere
2.2: 4 h / 20 °C / Schlenk technique; Inert atmosphere
3.1: ethylmagnesium bromide / tetrahydrofuran / 2 h / 60 °C / Schlenk technique
3.2: 60 °C
With
bis-triphenylphosphine-palladium(II) chloride; ethylmagnesium bromide; diisopropylamine;
In
tetrahydrofuran; dichloromethane;
2.1: |Sonogashira Cross-Coupling / 2.2: |Sonogashira Cross-Coupling;
DOI:10.1021/ja4049306
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: dichloromethane / 20 °C
2.1: bis-triphenylphosphine-palladium(II) chloride; diisopropylamine / tetrahydrofuran / 0.5 h / Schlenk technique; Inert atmosphere
2.2: 4 h / 20 °C / Schlenk technique; Inert atmosphere
3.1: ethylmagnesium bromide / tetrahydrofuran / 2 h / 60 °C / Schlenk technique
3.2: 60 °C
With
bis-triphenylphosphine-palladium(II) chloride; ethylmagnesium bromide; diisopropylamine;
In
tetrahydrofuran; dichloromethane;
2.1: |Sonogashira Cross-Coupling / 2.2: |Sonogashira Cross-Coupling;
DOI:10.1021/ja4049306
