C₆₃H₉₈O₁₄Si₂

Base Information

Chemical Name:C₆₃H₉₈O₁₄Si₂
CAS No.:500208-49-1
Molecular Formula:C₆₃H₉₈O₁₄Si₂
Molecular Weight:1135.63
Hs Code.:

C<sub>63</sub>H<sub>98</sub>O<sub>14</sub>Si<sub>2</sub>

Synonyms:C₆₃H₉₈O₁₄Si₂

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Chemical Property of C₆₃H₉₈O₁₄Si₂

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Technology Process of C₆₃H₉₈O₁₄Si₂

There total 7 articles about C₆₃H₉₈O₁₄Si₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 462117-19-7
Octanoic acid (2S,3S,6S)-6-[(R)-3-(tert-butyl-dimethyl-silanyloxy)-2-hydroxy-propyl]-2-((E)-1,1-dimethyl-4-oxo-but-2-enyl)-2-hydroxy-4-[1-methoxycarbonyl-meth-(E)-ylidene]-tetrahydro-pyran-3-yl ester

: 500208-41-3
3-(tert-butyldiphenylsilanyloxy)-4-[6-(2,2-dimethyl-[1,3]dioxan-4-ylmethyl)-tetrahydropyran-2-yl]-butyric acid

: 500208-49-1
C₆₃H₉₈O₁₄Si₂

Guidance literature:: With N-ethyl-N,N-diisopropylamine; bromo-tris(1-pyrrolidinyl)phosphonium hexafluorophosphate; In dichloromethane; at 20 ℃; for 3h;
DOI:10.1021/ol0272390

Reference yield:

: 500208-43-5
6-[4-benzyloxy-2-(tert-butyldiphenylsilanyloxy)-butyl]-tetrahydropyran-2-one

: 500208-49-1
C₆₃H₉₈O₁₄Si₂

Guidance literature:: Multi-step reaction with 7 steps

1.1: diisopropylamine; n-BuLi / tetrahydrofuran; hexane / -78 - 0 °C

1.2: tetrahydrofuran; hexane / 1 h / -78 °C

2.1: 278 g / triethylsilane; trifluoroacetic acid / CH₂Cl₂ / 4 h / -30 °C

3.1: 91 percent / hydrogen / Ru-R-(BINAP)Cl₂ / ethanol / 96 h / 20 °C / 58505.9 Torr

4.1: hydrogen / Pd(OH)2 / diethyl ether / 1 h / 760.05 Torr

4.2: 96 percent / lithium borohydride / diethyl ether / 1 h

5.1: 93 percent / PPTS / dimethylformamide / 3 h / 20 °C

6.1: 92 percent / TEMPO; NaClO₂; NaOCl / acetonitrile; H₂O; aq. phosphate buffer / 4 h / 45 °C / pH 7

7.1: 70 percent / PyBroP; diisopropylethylamine / CH₂Cl₂ / 3 h / 20 °C

With triethylsilane; 2,2,6,6-tetramethyl-piperidine-N-oxyl; sodium hypochlorite; sodium chlorite; n-butyllithium; hydrogen; pyridinium p-toluenesulfonate; diisopropylamine; N-ethyl-N,N-diisopropylamine; bromo-tris(1-pyrrolidinyl)phosphonium hexafluorophosphate; trifluoroacetic acid; palladium dihydroxide; RuCl₂[(R)-BINAP]; In tetrahydrofuran; phosphate buffer; diethyl ether; ethanol; hexane; dichloromethane; water; N,N-dimethyl-formamide; acetonitrile; 3.1: Noyori asymmetric hydrogenation;
DOI:10.1021/ol0272390

Reference yield:

: 4-{6-[4-benzyloxy-2-(tert-butyldiphenylsilanyloxy)-butyl]-2-hydroxytetrahydropyran-2-yl}-3-oxobutyric acid ethyl ester

: 500208-49-1
C₆₃H₉₈O₁₄Si₂

Guidance literature:: Multi-step reaction with 6 steps

1.1: 278 g / triethylsilane; trifluoroacetic acid / CH₂Cl₂ / 4 h / -30 °C

2.1: 91 percent / hydrogen / Ru-R-(BINAP)Cl₂ / ethanol / 96 h / 20 °C / 58505.9 Torr

3.1: hydrogen / Pd(OH)2 / diethyl ether / 1 h / 760.05 Torr

3.2: 96 percent / lithium borohydride / diethyl ether / 1 h

4.1: 93 percent / PPTS / dimethylformamide / 3 h / 20 °C

5.1: 92 percent / TEMPO; NaClO₂; NaOCl / acetonitrile; H₂O; aq. phosphate buffer / 4 h / 45 °C / pH 7

6.1: 70 percent / PyBroP; diisopropylethylamine / CH₂Cl₂ / 3 h / 20 °C

With triethylsilane; 2,2,6,6-tetramethyl-piperidine-N-oxyl; sodium hypochlorite; sodium chlorite; hydrogen; pyridinium p-toluenesulfonate; N-ethyl-N,N-diisopropylamine; bromo-tris(1-pyrrolidinyl)phosphonium hexafluorophosphate; trifluoroacetic acid; palladium dihydroxide; RuCl₂[(R)-BINAP]; In phosphate buffer; diethyl ether; ethanol; dichloromethane; water; N,N-dimethyl-formamide; acetonitrile; 2.1: Noyori asymmetric hydrogenation;
DOI:10.1021/ol0272390