trans-(2S,3S)-2-(p-cyanophenyl)-3-[(S)-2-(p-toluenesulfinyl)phenyl]-1-[(R)-(p-toluenesulfinyl)]aziridine

Base Information

Chemical Name:trans-(2S,3S)-2-(p-cyanophenyl)-3-[(S)-2-(p-toluenesulfinyl)phenyl]-1-[(R)-(p-toluenesulfinyl)]aziridine
CAS No.:1151538-52-1
Molecular Formula:C₂₉H₂₄N₂O₂S₂
Molecular Weight:496.654
Hs Code.:

Synonyms:trans-(2S,3S)-2-(p-cyanophenyl)-3-[(S)-2-(p-toluenesulfinyl)phenyl]-1-[(R)-(p-toluenesulfinyl)]aziridine

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Chemical Property of trans-(2S,3S)-2-(p-cyanophenyl)-3-[(S)-2-(p-toluenesulfinyl)phenyl]-1-[(R)-(p-toluenesulfinyl)]aziridine

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Technology Process of trans-(2S,3S)-2-(p-cyanophenyl)-3-[(S)-2-(p-toluenesulfinyl)phenyl]-1-[(R)-(p-toluenesulfinyl)]aziridine

There total 2 articles about trans-(2S,3S)-2-(p-cyanophenyl)-3-[(S)-2-(p-toluenesulfinyl)phenyl]-1-[(R)-(p-toluenesulfinyl)]aziridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: C₁₅H₁₂N₂OS

: 1151538-22-5
(S)-dimethyl[2-(p-toluenesulfinyl)phenyl]sulfonium perchlorate

: 1151538-52-1
trans-(2S,3S)-2-(p-cyanophenyl)-3-[(S)-2-(p-toluenesulfinyl)phenyl]-1-[(R)-(p-toluenesulfinyl)]aziridine

: 1151538-44-1
cis-(2R,3S)-2-(p-cyanophenyl)-3-[(S)-2-(p-toluenesulfinyl)phenyl]-1-[(R)-(p-toluenesulfinyl)]aziridine

Guidance literature:: (S)-dimethyl[2-(p-toluenesulfinyl)phenyl]sulfonium perchlorate; With lithium hexamethyldisilazane; In tetrahydrofuran; at -78 ℃; for 0.166667h; Inert atmosphere;

C₁₅H₁₂N₂OS; In tetrahydrofuran; at -78 ℃; for 0.166667h; optical yield given as %de; diastereoselective reaction; Inert atmosphere;
DOI:10.1021/jo900381b

Reference yield: 32.0%

: 1029690-05-8
(S)-2-(p-toluenesulfinyl)benzyl iodide

: 1151538-29-2
C₁₅H₁₂N₂OS

: 1151538-52-1
trans-(2S,3S)-2-(p-cyanophenyl)-3-[(S)-2-(p-toluenesulfinyl)phenyl]-1-[(R)-(p-toluenesulfinyl)]aziridine

: 1252974-68-7
cis-(2S,3R)-2-(p-cyanophenyl)-3-[(S)-2-(p-toluenesulfinyl)phenyl]-1-[(R)-(p-toluenesulfinyl)]aziridine

: 1252974-61-0
trans-(2R,3R)-2-(p-cyanophenyl)-3-[(S)-2-(p-toluenesulfinyl)phenyl]-1-[(R)-(p-toluenesulfinyl)]aziridine

Guidance literature:: With sodium hexamethyldisilazane; In tetrahydrofuran; at -78 ℃; for 0.0166667h; optical yield given as %de; diastereoselective reaction; Inert atmosphere;
DOI:10.1002/chem.201000217