(R,E)-allyl-5-methyl-2-[(triisopropylsilyloxy)methyl]hex-3-enyl carbamic acid benzyl ester

Base Information

Chemical Name:(R,E)-allyl-5-methyl-2-[(triisopropylsilyloxy)methyl]hex-3-enyl carbamic acid benzyl ester
CAS No.:855297-98-2
Molecular Formula:C₂₈H₄₇NO₃Si
Molecular Weight:473.772
Hs Code.:

Synonyms:(R,E)-allyl-5-methyl-2-[(triisopropylsilyloxy)methyl]hex-3-enyl carbamic acid benzyl ester

Suppliers and Price of (R,E)-allyl-5-methyl-2-[(triisopropylsilyloxy)methyl]hex-3-enyl carbamic acid benzyl ester

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (R,E)-allyl-5-methyl-2-[(triisopropylsilyloxy)methyl]hex-3-enyl carbamic acid benzyl ester

Chemical Property:

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Technology Process of (R,E)-allyl-5-methyl-2-[(triisopropylsilyloxy)methyl]hex-3-enyl carbamic acid benzyl ester

There total 6 articles about (R,E)-allyl-5-methyl-2-[(triisopropylsilyloxy)methyl]hex-3-enyl carbamic acid benzyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (E)-(R)-2-Aminomethyl-5-methyl-hex-3-en-1-ol

: 855297-98-2
(R,E)-allyl-5-methyl-2-[(triisopropylsilyloxy)methyl]hex-3-enyl carbamic acid benzyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 0 °C / pH 9 - 10

2: 89 percent / imidazole / dimethylformamide / 20 °C

3: 81 percent / NaH / dimethylformamide / 20 °C

With 1H-imidazole; sodium hydride; In N,N-dimethyl-formamide;
DOI:10.1039/b502952j

Reference yield:

: 521917-97-5
(R,E)-2-azidomethyl-5-methylhex-3-enyl ester acetate

: 855297-98-2
(R,E)-allyl-5-methyl-2-[(triisopropylsilyloxy)methyl]hex-3-enyl carbamic acid benzyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: 97 percent / Pseudomonas cepacia lipase / tetrahydrofuran; aq. phosphate buffer / 19 h / 20 °C / pH 7

2: aq. PPh₃ / tetrahydrofuran / 8 h / 20 °C

3: 0 °C / pH 9 - 10

4: 89 percent / imidazole / dimethylformamide / 20 °C

5: 81 percent / NaH / dimethylformamide / 20 °C

With 1H-imidazole; Pseudomonas cepacia lipase; sodium hydride; triphenylphosphine; In tetrahydrofuran; phosphate buffer; N,N-dimethyl-formamide; 2: Staudinger reduction;
DOI:10.1039/b502952j

Reference yield:

: 521917-99-7
(R,E)-2-azidomethyl-5-methylhex-3-en-1-ol

: 855297-98-2
(R,E)-allyl-5-methyl-2-[(triisopropylsilyloxy)methyl]hex-3-enyl carbamic acid benzyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: aq. PPh₃ / tetrahydrofuran / 8 h / 20 °C

2: 0 °C / pH 9 - 10

3: 89 percent / imidazole / dimethylformamide / 20 °C

4: 81 percent / NaH / dimethylformamide / 20 °C

With 1H-imidazole; sodium hydride; triphenylphosphine; In tetrahydrofuran; N,N-dimethyl-formamide; 1: Staudinger reduction;
DOI:10.1039/b502952j