phenyl 3,5-O-(di-tert-butylsilylene)-2-O-trifluoroacetyl-1-thio-α-D-arabinofuranoside

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Chemical Name:phenyl 3,5-O-(di-tert-butylsilylene)-2-O-trifluoroacetyl-1-thio-α-D-arabinofuranoside
CAS No.:1621691-66-4
Molecular Formula:C₂₁H₂₉F₃O₅SSi
Molecular Weight:478.605
Hs Code.:

Synonyms:phenyl 3,5-O-(di-tert-butylsilylene)-2-O-trifluoroacetyl-1-thio-α-D-arabinofuranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of phenyl 3,5-O-(di-tert-butylsilylene)-2-O-trifluoroacetyl-1-thio-α-D-arabinofuranoside

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Technology Process of phenyl 3,5-O-(di-tert-butylsilylene)-2-O-trifluoroacetyl-1-thio-α-D-arabinofuranoside

There total 1 articles about phenyl 3,5-O-(di-tert-butylsilylene)-2-O-trifluoroacetyl-1-thio-α-D-arabinofuranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 1096610-41-1
phenyl 3,5-O-(di-tert-butylsilanediyl)-1-thio-α-D-arabinofuranoside

: 407-25-0
trifluoroacetic anhydride

: 1621691-66-4
phenyl 3,5-O-(di-tert-butylsilylene)-2-O-trifluoroacetyl-1-thio-α-D-arabinofuranoside

Guidance literature:: With sodium 2,2,2-trifluoroacetate; In dichloromethane; at 0 ℃; for 1h;
DOI:10.1016/j.carres.2014.05.017

Reference yield:

: 1621691-68-6
4-(2-chloroethoxy)phenyl 3,5-di-O-benzoyl-α-D-arabinofuranoside

: 1621691-66-4
phenyl 3,5-O-(di-tert-butylsilylene)-2-O-trifluoroacetyl-1-thio-α-D-arabinofuranoside

: 1621691-86-8
4-(2-chloroethoxy)phenyl 3,5-di-O-benzoyl-2-O-[3,5-O-(di-tert-butylsilylene)-α-D-arabinofuranosyl]-α-D-arabinofuranoside

: 1621691-85-7
4-(2-chloroethoxy)phenyl 3,5-di-O-benzoyl-2-O-[3,5-O-(di-tert-butylsilylene)-β-D-arabinofuranosyl]-α-D-arabinofuranoside

Guidance literature:: 4-(2-chloroethoxy)phenyl 3,5-di-O-benzoyl-α-D-arabinofuranoside; phenyl 3,5-O-(di-tert-butylsilylene)-2-O-trifluoroacetyl-1-thio-α-D-arabinofuranoside; In dichloromethane; at 22 ℃; for 1h; Inert atmosphere; Molecular sieve;

With N-iodo-succinimide; silver trifluoromethanesulfonate; In dichloromethane; at -78 - 10 ℃; for 1h; Overall yield = 66 %; Inert atmosphere; Molecular sieve;
DOI:10.1016/j.carres.2014.05.017