tert-butyl{(2S,4R,6S)-2-(iodomethyl)-6-[((2R,4S,6R)-6-(iodomethyl)-4-(methoxymethoxy)tetrahydro-2H-pyran-2-yl)methyl]tetrahydro-2H-pyran-4-yloxy}diphenylsilane

Base Information

Chemical Name:tert-butyl{(2S,4R,6S)-2-(iodomethyl)-6-[((2R,4S,6R)-6-(iodomethyl)-4-(methoxymethoxy)tetrahydro-2H-pyran-2-yl)methyl]tetrahydro-2H-pyran-4-yloxy}diphenylsilane
CAS No.:1613145-03-1
Molecular Formula:C₃₁H₄₄I₂O₅Si
Molecular Weight:778.582
Hs Code.:

tert-butyl{(2S,4R,6S)-2-(iodomethyl)-6-[((2R,4S,6R)-6-(iodomethyl)-4-(methoxymethoxy)tetrahydro-2H-pyran-2-yl)methyl]tetrahydro-2H-pyran-4-yloxy}diphenylsilane

Synonyms:tert-butyl{(2S,4R,6S)-2-(iodomethyl)-6-[((2R,4S,6R)-6-(iodomethyl)-4-(methoxymethoxy)tetrahydro-2H-pyran-2-yl)methyl]tetrahydro-2H-pyran-4-yloxy}diphenylsilane

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Chemical Property of tert-butyl{(2S,4R,6S)-2-(iodomethyl)-6-[((2R,4S,6R)-6-(iodomethyl)-4-(methoxymethoxy)tetrahydro-2H-pyran-2-yl)methyl]tetrahydro-2H-pyran-4-yloxy}diphenylsilane

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Technology Process of tert-butyl{(2S,4R,6S)-2-(iodomethyl)-6-[((2R,4S,6R)-6-(iodomethyl)-4-(methoxymethoxy)tetrahydro-2H-pyran-2-yl)methyl]tetrahydro-2H-pyran-4-yloxy}diphenylsilane

There total 3 articles about tert-butyl{(2S,4R,6S)-2-(iodomethyl)-6-[((2R,4S,6R)-6-(iodomethyl)-4-(methoxymethoxy)tetrahydro-2H-pyran-2-yl)methyl]tetrahydro-2H-pyran-4-yloxy}diphenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 1613144-95-8
(2S,4S,6R)-2-{[(2S,4R,6S)-4-(tert-butyldiphenylsilyl)oxy-6-(iodomethyl)tetrahydro-2H-pyran-2-yl]methyl}-6-(iodomethyl)tetrahydro-2H-pyran-4-ol

: 107-30-2
chloromethyl methyl ether

: 1613145-03-1
tert-butyl{(2S,4R,6S)-2-(iodomethyl)-6-[((2R,4S,6R)-6-(iodomethyl)-4-(methoxymethoxy)tetrahydro-2H-pyran-2-yl)methyl]tetrahydro-2H-pyran-4-yloxy}diphenylsilane

Guidance literature:: With N-ethyl-N,N-diisopropylamine; In dichloromethane; at 20 ℃; for 18h; Inert atmosphere;
DOI:10.1039/c4cc02702g

Reference yield:

: 1613144-85-6
{(2S,4R,6S)-4-[(tert-butyldiphenylsilyl)oxy]-6-[((2S,4S,6R)-4-hydroxy-6-(tosyloxymethyl)tetrahydro-2H-pyran-2-yl)methyl]tetrahydro-2H-pyran-2-yl}methyl 4-methylbenzenesulfonate

: 1613145-03-1
tert-butyl{(2S,4R,6S)-2-(iodomethyl)-6-[((2R,4S,6R)-6-(iodomethyl)-4-(methoxymethoxy)tetrahydro-2H-pyran-2-yl)methyl]tetrahydro-2H-pyran-4-yloxy}diphenylsilane

Guidance literature:: Multi-step reaction with 2 steps

1: sodium iodide / acetone / 2 h / 120 °C / Inert atmosphere; Microwave irradiation; Sealed tube

2: N-ethyl-N,N-diisopropylamine / dichloromethane / 18 h / 20 °C / Inert atmosphere

With N-ethyl-N,N-diisopropylamine; sodium iodide; In dichloromethane; acetone;
DOI:10.1039/c4cc02702g

Reference yield:

: 501365-06-6
(R)-2-hydroxypent-4-en-1-yl 4-methylbenzenesulfonate

: 1613145-03-1
tert-butyl{(2S,4R,6S)-2-(iodomethyl)-6-[((2R,4S,6R)-6-(iodomethyl)-4-(methoxymethoxy)tetrahydro-2H-pyran-2-yl)methyl]tetrahydro-2H-pyran-4-yloxy}diphenylsilane

Guidance literature:: Multi-step reaction with 3 steps

1.1: trifluoroacetic acid / dichloromethane / 3 h / 20 °C / Inert atmosphere

1.2: 2 h / 20 °C / pH > 7 / Inert atmosphere

2.1: sodium iodide / acetone / 2 h / 120 °C / Inert atmosphere; Microwave irradiation; Sealed tube

3.1: N-ethyl-N,N-diisopropylamine / dichloromethane / 18 h / 20 °C / Inert atmosphere

With N-ethyl-N,N-diisopropylamine; trifluoroacetic acid; sodium iodide; In dichloromethane; acetone;
DOI:10.1039/c4cc02702g