C₄₉H₅₈O₁₄SSi

Base Information

• Chemical Name: C₄₉H₅₈O₁₄SSi
• CAS No.: 192126-03-7
• Molecular Formula: C₄₉H₅₈O₁₄SSi
• Molecular Weight: 931.143
• Mol file: 192126-03-7.mol

Synonyms:C₄₉H₅₈O₁₄SSi

Chemical Property of C₄₉H₅₈O₁₄SSi

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of C₄₉H₅₈O₁₄SSi

There total 5 articles about C₄₉H₅₈O₁₄SSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

2,3,4,6-tetra-O-benzoyl-1-O-trichloroacetimidoyl-α-D-galactopyranose (149707-75-5,149707-76-6,138479-78-4) + 3-{6-[(2-Hydroxy-ethyl)-dimethyl-silanyl]-hexane-1-sulfonyl}-propionic acid ethyl ester (192126-02-6) → C49H58O14SSi (192126-03-7)

Guidance literature:

With trimethylsilyl trifluoromethanesulfonate; In n-heptane; dichloromethane; for 0.333333h;

DOI:10.1016/S0040-4039(97)00880-0

Reference yield:

3-mercaptopropionic acid ethyl ester (5466-06-8) → C49H58O14SSi (192126-03-7)

Guidance literature:

Multi-step reaction with 3 steps

1: 88 percent / AIBN / benzene / 89 h / Irradiation

2: 89 percent / MCPBA / ethyl acetate / 4 h

3: 77 percent / TMS-triflate / CH₂Cl₂; heptane / 0.33 h

With 2,2'-azobis(isobutyronitrile); trimethylsilyl trifluoromethanesulfonate; 3-chloro-benzenecarboperoxoic acid; In n-heptane; dichloromethane; ethyl acetate; benzene;

DOI:10.1016/S0040-4039(97)00880-0

Reference yield:

6-hex-1-enyldimethylchlorosilane (30102-73-9) → C49H58O14SSi (192126-03-7)

Guidance literature:

Multi-step reaction with 4 steps

1: 1.) Zn, 2.) LiAlH₄ / 1.) toluene/Et₂O 4:1, reflux, 75 min, 2.) Et₂O, 10 min, 0 deg C and 45 min, reflux

2: 88 percent / AIBN / benzene / 89 h / Irradiation

3: 89 percent / MCPBA / ethyl acetate / 4 h

4: 77 percent / TMS-triflate / CH₂Cl₂; heptane / 0.33 h

With lithium aluminium tetrahydride; 2,2'-azobis(isobutyronitrile); trimethylsilyl trifluoromethanesulfonate; 3-chloro-benzenecarboperoxoic acid; zinc; In n-heptane; dichloromethane; ethyl acetate; benzene;

DOI:10.1016/S0040-4039(97)00880-0

upstream raw materials:

2,3,4,6-tetra-O-benzoyl-1-O-trichloroacetimidoyl-α-D-galactopyranose

3-{6-[(2-Hydroxy-ethyl)-dimethyl-silanyl]-hexane-1-sulfonyl}-propionic acid ethyl ester

3-mercaptopropionic acid ethyl ester

6-hex-1-enyldimethylchlorosilane

Downstream raw materials:

1-O-acetyl-2,3,4,6-tetra-O-benzoyl-β-D-galactopyranose