[(1S,2S,4S,5S)-2-Benzyloxymethyl-5-methoxy-4-(4-methoxy-benzyloxy)-2-methyl-cyclopentyloxy]-tert-butyl-dimethyl-silane

Base Information

Chemical Name:[(1S,2S,4S,5S)-2-Benzyloxymethyl-5-methoxy-4-(4-methoxy-benzyloxy)-2-methyl-cyclopentyloxy]-tert-butyl-dimethyl-silane
CAS No.:247589-96-4
Molecular Formula:C₂₉H₄₄O₅Si
Molecular Weight:500.751
Hs Code.:

Synonyms:[(1S,2S,4S,5S)-2-Benzyloxymethyl-5-methoxy-4-(4-methoxy-benzyloxy)-2-methyl-cyclopentyloxy]-tert-butyl-dimethyl-silane

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Chemical Property of [(1S,2S,4S,5S)-2-Benzyloxymethyl-5-methoxy-4-(4-methoxy-benzyloxy)-2-methyl-cyclopentyloxy]-tert-butyl-dimethyl-silane

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Technology Process of [(1S,2S,4S,5S)-2-Benzyloxymethyl-5-methoxy-4-(4-methoxy-benzyloxy)-2-methyl-cyclopentyloxy]-tert-butyl-dimethyl-silane

There total 7 articles about [(1S,2S,4S,5S)-2-Benzyloxymethyl-5-methoxy-4-(4-methoxy-benzyloxy)-2-methyl-cyclopentyloxy]-tert-butyl-dimethyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: (2S,3S,5S)-3-Benzyloxymethyl-2-(tert-butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxy)-3-methyl-cyclopentanol

: 74-88-4
methyl iodide

: 247589-96-4
[(1S,2S,4S,5S)-2-Benzyloxymethyl-5-methoxy-4-(4-methoxy-benzyloxy)-2-methyl-cyclopentyloxy]-tert-butyl-dimethyl-silane

Guidance literature:: With sodium hydride; at 0 ℃;
DOI:10.1039/a903160j

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 247589-96-4
[(1S,2S,4S,5S)-2-Benzyloxymethyl-5-methoxy-4-(4-methoxy-benzyloxy)-2-methyl-cyclopentyloxy]-tert-butyl-dimethyl-silane

Guidance literature:: Multi-step reaction with 3 steps

1: 96 percent / imidazole; DMAP

2: 100 percent / K₂CO₃ / methanol

3: 86 percent / NaH / 0 °C

With 1H-imidazole; dmap; sodium hydride; potassium carbonate; In methanol; 1: Etherification / 2: Deacetylation / 3: Methylation;
DOI:10.1039/a903160j

Reference yield:

: 247589-92-0
(3aS,4S,6S,6aR)-4-Benzyloxymethyl-6-(4-methoxy-benzyloxy)-4-methyl-tetrahydro-cyclopenta[1,3,2]dioxathiole 2,2-dioxide

: 247589-96-4
[(1S,2S,4S,5S)-2-Benzyloxymethyl-5-methoxy-4-(4-methoxy-benzyloxy)-2-methyl-cyclopentyloxy]-tert-butyl-dimethyl-silane

Guidance literature:: Multi-step reaction with 4 steps

1.1: dimethylformamide / 40 °C

1.2: H₂SO₄ / tetrahydrofuran

2.1: 96 percent / imidazole; DMAP

3.1: 100 percent / K₂CO₃ / methanol

4.1: 86 percent / NaH / 0 °C

With 1H-imidazole; dmap; sodium hydride; potassium carbonate; In methanol; N,N-dimethyl-formamide; 1.1: Substitution / 1.2: Hydrolysis / 2.1: Etherification / 3.1: Deacetylation / 4.1: Methylation;
DOI:10.1039/a903160j