Technology Process of 9-(2,2-(2)H2-Ethyl)10-phenylanthracene
There total 6 articles about 9-(2,2-(2)H2-Ethyl)10-phenylanthracene which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
tri-n-butyl-tin hydride;
In
benzene;
at 70 ℃;
for 8h;
Yield given. Yields of byproduct given. Title compound not separated from byproducts;
DOI:10.1021/ja00202a010
- Guidance literature:
-
Multi-step reaction with 6 steps
1: 78 percent / dimethylsulfoxide; H2O / 1 h / 60 °C
2: 70 percent / NaOH / 2-ethoxy-ethanol / 3 h / Heating
3: 90 percent / conc. H2SO4, Na2SO4 / 24 h / Heating
4: 94 percent / LiAlD4 / diethyl ether / 4 h / Ambient temperature
5: 72 percent / PBr3 / benzene / 1 h / Heating
6: tri-n-butyltin hydride, DPDC / benzene / 8 h / 70 °C
With
sodium hydroxide; lithium aluminium deuteride; sulfuric acid; tri-n-butyl-tin hydride; phosphorus tribromide; sodium sulfate;
In
2-ethoxy-ethanol; diethyl ether; water; dimethyl sulfoxide; benzene;
DOI:10.1021/ja00202a010
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 70 percent / NaOH / 2-ethoxy-ethanol / 3 h / Heating
2: 90 percent / conc. H2SO4, Na2SO4 / 24 h / Heating
3: 94 percent / LiAlD4 / diethyl ether / 4 h / Ambient temperature
4: 72 percent / PBr3 / benzene / 1 h / Heating
5: tri-n-butyltin hydride, DPDC / benzene / 8 h / 70 °C
With
sodium hydroxide; lithium aluminium deuteride; sulfuric acid; tri-n-butyl-tin hydride; phosphorus tribromide; sodium sulfate;
In
2-ethoxy-ethanol; diethyl ether; benzene;
DOI:10.1021/ja00202a010
