2-[(2,4-dinitrophenyl)thio]-N,N-dimethylbenzenemethaneamine

Base Information

• Chemical Name: 2-[(2,4-dinitrophenyl)thio]-N,N-dimethylbenzenemethaneamine
• CAS No.: 606937-73-9
• Molecular Formula: C₁₅H₁₅N₃O₄S
• Molecular Weight: 333.368
• Mol file: 606937-73-9.mol

Synonyms:2-[(2,4-dinitrophenyl)thio]-N,N-dimethylbenzenemethaneamine

Chemical Property of 2-[(2,4-dinitrophenyl)thio]-N,N-dimethylbenzenemethaneamine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-[(2,4-dinitrophenyl)thio]-N,N-dimethylbenzenemethaneamine

There total 6 articles about 2-[(2,4-dinitrophenyl)thio]-N,N-dimethylbenzenemethaneamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

N,N-dimethyl-2-(2,4-dinitrophenylthio)benzylamine.BH3 (606937-72-8) → 2-[(2,4-dinitrophenyl)thio]-N,N-dimethylbenzenemethaneamine (606937-73-9)

Guidance literature:

N,N-dimethyl-2-(2,4-dinitrophenylthio)benzylamine.BH₃; With hydrogenchloride; In methanol; for 2h; Reflux;

With sodium hydrogencarbonate; In water; pH=8;

Reference yield: 52.0%

2-[(2,4-dinitrophenyl)thio]-N,N-dimethylbenzamide (606937-71-7) → 2-[(2,4-dinitrophenyl)thio]-N,N-dimethylbenzenemethaneamine (606937-73-9)

Guidance literature:

With borane-THF; In tetrahydrofuran; at 70 ℃;

DOI:10.1021/jm0400808

Reference yield:

2-(2,4-dinitrophenylthio)benzoyl chloride → 2-[(2,4-dinitrophenyl)thio]-N,N-dimethylbenzenemethaneamine (606937-73-9)

Guidance literature:

Multi-step reaction with 2 steps

1: K₂CO₃ / tetrahydrofuran / 20 °C

2: 52 percent / BH₃*THF / tetrahydrofuran / 70 °C

With borane-THF; potassium carbonate; In tetrahydrofuran;

DOI:10.1021/jm0400808

upstream raw materials:

2-[(2,4-dinitrophenyl)thio]-N,N-dimethylbenzamide

2,4-dinitrobromobenzene

2-(2,4-dinitro-phenylsulfanyl)-benzoic acid

Thiosalicylic acid