4-(3,5-di-tert-butyl-4-acetoxyphenyl)-m-bis(2'-methyl-5'-(3'',5''-di-tert-butylacetoxyphenyl))benzene

Base Information

• Chemical Name: 4-(3,5-di-tert-butyl-4-acetoxyphenyl)-m-bis(2'-methyl-5'-(3'',5''-di-tert-butylacetoxyphenyl))benzene
• CAS No.: 352565-57-2
• Molecular Formula: C₇₂H₈₈O₆
• Molecular Weight: 1049.49
• Mol file: 352565-57-2.mol

Synonyms:4-(3,5-di-tert-butyl-4-acetoxyphenyl)-m-bis(2'-methyl-5'-(3'',5''-di-tert-butylacetoxyphenyl))benzene

Chemical Property of 4-(3,5-di-tert-butyl-4-acetoxyphenyl)-m-bis(2'-methyl-5'-(3'',5''-di-tert-butylacetoxyphenyl))benzene

Chemical Property:

Purity/Quality:

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MSDS Files:

Useful:

Technology Process of 4-(3,5-di-tert-butyl-4-acetoxyphenyl)-m-bis(2'-methyl-5'-(3'',5''-di-tert-butylacetoxyphenyl))benzene

There total 1 articles about 4-(3,5-di-tert-butyl-4-acetoxyphenyl)-m-bis(2'-methyl-5'-(3'',5''-di-tert-butylacetoxyphenyl))benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

2-bromo-4-(3,5-di-tert-butyl-4-acetoxyphenyl)toluene + 4-(3,5-di-tert-butyl-4-acetoxyphenyl)-1,3-divinylbenzene → 4-(3,5-di-tert-butyl-4-acetoxyphenyl)-m-bis(2'-methyl-5'-(3'',5''-di-tert-butylacetoxyphenyl))benzene (352565-57-2)

Guidance literature:

With palladium diacetate; triethylamine; tris-(o-tolyl)phosphine; In N,N-dimethyl-formamide;

DOI:10.1021/ja002944u

Reference yield: 73.0%

4-(3,5-di-tert-butyl-4-acetoxyphenyl)-m-bis(2'-methyl-5'-(3'',5''-di-tert-butylacetoxyphenyl))benzene (352565-57-2) → 4-(3,5-di-tert-butyl-4-hydroxyphenyl)-m-bis(2'-methyl-5'-(3'',5''-di-tert-butylhydroxyphenyl))benzene (352565-66-3)

Guidance literature:

With potassium hydroxide; In tetrahydrofuran; dimethyl sulfoxide; at 40 - 50 ℃; for 15h;

DOI:10.1021/ja002944u

Reference yield:

4-(3,5-di-tert-butyl-4-acetoxyphenyl)-m-bis(2'-methyl-5'-(3'',5''-di-tert-butylacetoxyphenyl))benzene (352565-57-2) → C66H79O3

Guidance literature:

Multi-step reaction with 2 steps

1.1: 73 percent / aq. KOH / tetrahydrofuran; dimethylsulfoxide / 15 h / 40 - 50 °C

2.1: aq. NaOH / various solvent(s) / 0.5 h

2.2: aq. K₃[Fe(CN)6] / various solvent(s) / 20 °C

With potassium hydroxide; sodium hydroxide; In tetrahydrofuran; dimethyl sulfoxide;

DOI:10.1021/ja002944u

Downstream raw materials:

4-(3,5-di-tert-butyl-4-hydroxyphenyl)-m-bis(2'-methyl-5'-(3'',5''-di-tert-butylhydroxyphenyl))benzene