[(η5-C5H5)(PPh3)2Ru(-C2-C(Ph)2CH2C2H)]

Base Information

Chemical Name:[(η5-C5H5)(PPh3)2Ru(-C2-C(Ph)2CH2C2H)]
CAS No.:874300-18-2
Molecular Formula:C₅₉H₄₈P₂Ru
Molecular Weight:920.048
Hs Code.:

Synonyms:[(η5-C5H5)(PPh3)2Ru(-C2-C(Ph)2CH2C2H)]

Suppliers and Price of [(η5-C5H5)(PPh3)2Ru(-C2-C(Ph)2CH2C2H)]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [(η5-C5H5)(PPh3)2Ru(-C2-C(Ph)2CH2C2H)]

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [(η5-C5H5)(PPh3)2Ru(-C2-C(Ph)2CH2C2H)]

There total 1 articles about [(η5-C5H5)(PPh3)2Ru(-C2-C(Ph)2CH2C2H)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 220697-78-9
[Ru(C=C=CPh₂)(PPh₃)2Cp][PF₆]

: 18295-60-8
propargyl magnesium bromide

: 874300-18-2
[(η5-C5H5)(PPh3)2Ru(-C2-C(Ph)2CH2C2H)]

Guidance literature:: In tetrahydrofuran; diethyl ether; (N2); Mg compd. in Et2O added to a THF soln. of Ru complex, stirred at -20°C, warmed to room temp.; evapd. (vac.), dissolved in CH2Cl2, MeOH added, concd., filtered, washed(cold MeOH), dried (vac.); elem. anal.;
DOI:10.1021/ja054994a

Reference yield: 94.0%

: tetrafluoroboric acid

: 874300-18-2
[(η5-C5H5)(PPh3)2Ru(-C2-C(Ph)2CH2C2H)]

: [(η5-C5H5)(PPh3)2Ru(=C=CHC(Ph)2CH2C2H)]BF4

Guidance literature:: In diethyl ether; (N2); HBF4 in Et2O added dropwise at 0°C to Ru complex in Et2O; filtered, washed (Et2O), dried (vac.); elem. anal.;
DOI:10.1021/ja054994a

Reference yield: 88.0%

: 26042-64-8
silver hexafluoroantimonate

: 874300-18-2
[(η5-C5H5)(PPh3)2Ru(-C2-C(Ph)2CH2C2H)]

: [Cp(PPh₃)2RuC₆H₄Ph₂][SbF₆]

Guidance literature:: triphenylphosphinogold(I) hexafluoroantimonate; In dichloromethane; water; under N2; a soln. of Ag- (0.05 mmol) and Au-contg. (0.05 mmol) compds. in wet CH2Cl2 was stirred at room temp. for 10 min; addn. of a soln. of Ru-contg. compd. (0.11 mmol) in wet CH2Cl2; stirring at room temp. for 1.5 h; the soln. was filtered through Celite; the solid was dissolved in CH2Cl2; the solvent was reduced under rotary evapn.; addn. of Et2O for pptn.; the ppt. was filtered and washed with Et2O/hexane and dried under vac.; elem. anal.;
DOI:10.1021/om101017p