CpTi(OC₆H₃-2,6-i-Pr₂)2Cl

Base Information

• Chemical Name: CpTi(OC₆H₃-2,6-i-Pr₂)2Cl
• CAS No.: 207740-61-2
• Molecular Formula: C₂₉H₃₉ClO₂Ti
• Molecular Weight: 502.96
• Mol file: 207740-61-2.mol

Synonyms:CpTi(OC₆H₃-2,6-i-Pr₂)2Cl

Chemical Property of CpTi(OC₆H₃-2,6-i-Pr₂)2Cl

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of CpTi(OC₆H₃-2,6-i-Pr₂)2Cl

There total 1 articles about CpTi(OC₆H₃-2,6-i-Pr₂)2Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

cyclopentadienyl titanium(IV) trichloride (1270-98-0) + 2,6-diisopropylphenol (2078-54-8) → CpTi(OC6H3-2,6-i-Pr2)2Cl (207740-61-2)

Guidance literature:

With imidazole; In benzene; N2-atmosphere; 2 equiv. of diisopropylphenol, stirring overnight; filtration, solvent removal, crystn. (hexane); elem. anal.;

DOI:10.1016/S0022-328X(99)00422-2

Reference yield: 80.0%

lithium sulfide + CpTi(OC6H3-2,6-i-Pr2)2Cl (207740-61-2) → [CpTi(OC6H3-2,6-i-Pr2)2]2(μ-S) (213040-91-6)

Guidance literature:

In tetrahydrofuran; N2-atmosphere; stirring for 12 h; solvent removal (vac.), dissoln. in C6H6, filtration, evapn.; elem. anal.;

Reference yield: 40.0%

CpTi(OC6H3-2,6-i-Pr2)2Cl (207740-61-2) + sec.-butyllithium (598-30-1) → (C5H5)Ti(CH(CH3)C2H5)(OC6H3(CH(CH3)2)2)2 (256394-25-9)

Guidance literature:

In hexane; N2-atmosphere; dropwise addn. of 1 equiv. alkyllithium to Ti-complex, stirring for few min; filtration, concn., crystn.;

DOI:10.1016/S0022-328X(99)00422-2

upstream raw materials:

cyclopentadienyl titanium(IV) trichloride

2,6-diisopropylphenol

Downstream raw materials:

(C₅H₅)Ti(CH(CH₃)C₂H₅)(OC₆H₃(CH(CH₃)2)2)2

[(η5-C5H5)Ti(OC6H3(i-Pr)2-2,6)Me2]

(C₅H₅)Ti(C(CH₃)3)(OC₆H₃(CH(CH₃)2)2)2

[CpTi(OC6H3-2,6-i-Pr2)2]2(μ-S)