2-bromo-2-methyl-1-benzylthiomethylcyclopropane

Base Information

Chemical Name:2-bromo-2-methyl-1-benzylthiomethylcyclopropane
CAS No.:344287-80-5
Molecular Formula:C₁₂H₁₅BrS
Molecular Weight:271.221
Hs Code.:

Synonyms:2-bromo-2-methyl-1-benzylthiomethylcyclopropane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-bromo-2-methyl-1-benzylthiomethylcyclopropane

Chemical Property:

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Technology Process of 2-bromo-2-methyl-1-benzylthiomethylcyclopropane

There total 3 articles about 2-bromo-2-methyl-1-benzylthiomethylcyclopropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

: 917-54-4
methyllithium

: 81187-49-7
benzyl (2,2-dibromocyclopropyl)methyl sulphide

: 344287-80-5
2-bromo-2-methyl-1-benzylthiomethylcyclopropane

: 85034-34-0
2,3'-bis(benzylthiomethyl)-1,1'-bicyclopropylidene

: 85034-31-7,85081-65-8
endo-2-phenyl-3-thiabicyclo<3.1.0>hexane

: 85034-31-7,85081-65-8
exo-2-phenyl-3-thiabicyclo<3.1.0>hexane

Guidance literature:: In diethyl ether; at -78 ℃; for 1h; Further byproducts given. Yields of byproduct given;

Reference yield:

: 81187-49-7
benzyl (2,2-dibromocyclopropyl)methyl sulphide

: 344287-80-5
2-bromo-2-methyl-1-benzylthiomethylcyclopropane

: 85034-34-0
2,3'-bis(benzylthiomethyl)-1,1'-bicyclopropylidene

: 85034-31-7,85081-65-8
endo-2-phenyl-3-thiabicyclo<3.1.0>hexane

: 85034-31-7,85081-65-8
exo-2-phenyl-3-thiabicyclo<3.1.0>hexane

Guidance literature:: With methyllithium; In diethyl ether; at -78 ℃; for 1h; Further byproducts given. Yields of byproduct given;

Reference yield:

: 917-54-4
methyllithium

: 81187-49-7
benzyl (2,2-dibromocyclopropyl)methyl sulphide

: 85034-30-6
4-benzylthio-1,2-butadiene

: 344287-80-5
2-bromo-2-methyl-1-benzylthiomethylcyclopropane

: 85034-34-0
2,3'-bis(benzylthiomethyl)-1,1'-bicyclopropylidene

: 85034-31-7,85081-65-8
endo-2-phenyl-3-thiabicyclo<3.1.0>hexane

: 85034-31-7,85081-65-8
exo-2-phenyl-3-thiabicyclo<3.1.0>hexane

Guidance literature:: In diethyl ether; at -78 ℃; for 1h; Product distribution; reaction at 0 deg C; reactions of gem-dibromocyclopropylmethylsulfides with MeLi, effect of reaction temperature on product distribution, possible mechanism;