tert-butyl N-{[5-bromo-2-(prop-2-en-1-yloxy)phenyl](3,3-dimethylcycloprop-1-en-1-yl)methyl}carbamate

Base Information

Chemical Name:tert-butyl N-{[5-bromo-2-(prop-2-en-1-yloxy)phenyl](3,3-dimethylcycloprop-1-en-1-yl)methyl}carbamate
CAS No.:1314234-88-2
Molecular Formula:C₂₀H₂₆BrNO₃
Molecular Weight:408.335
Hs Code.:

Synonyms:tert-butyl N-{[5-bromo-2-(prop-2-en-1-yloxy)phenyl](3,3-dimethylcycloprop-1-en-1-yl)methyl}carbamate

Suppliers and Price of tert-butyl N-{[5-bromo-2-(prop-2-en-1-yloxy)phenyl](3,3-dimethylcycloprop-1-en-1-yl)methyl}carbamate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of tert-butyl N-{[5-bromo-2-(prop-2-en-1-yloxy)phenyl](3,3-dimethylcycloprop-1-en-1-yl)methyl}carbamate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of tert-butyl N-{[5-bromo-2-(prop-2-en-1-yloxy)phenyl](3,3-dimethylcycloprop-1-en-1-yl)methyl}carbamate

There total 3 articles about tert-butyl N-{[5-bromo-2-(prop-2-en-1-yloxy)phenyl](3,3-dimethylcycloprop-1-en-1-yl)methyl}carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 1314234-86-0
tert-butyl N-[5-bromo-2-(prop-2-en-1-yloxy)phenyl]methylidenecarbamate

: 23534-97-6
1,1,3‐tribromo‐2,2‐dimethylcyclopropane

: 1314234-88-2
tert-butyl N-{[5-bromo-2-(prop-2-en-1-yloxy)phenyl](3,3-dimethylcycloprop-1-en-1-yl)methyl}carbamate

Guidance literature:: 1,1,3‐tribromo‐2,2‐dimethylcyclopropane; With n-butyllithium; In hexanes; diethyl ether; at -78 - -10 ℃; for 1h;

tert-butyl N-[5-bromo-2-(prop-2-en-1-yloxy)phenyl]methylidenecarbamate; In tetrahydrofuran; hexanes; diethyl ether; at -50 - 20 ℃; for 0.25h;

With ammonium chloride; In hexanes; diethyl ether; water; Saturated solution;
DOI:10.1002/anie.201101220

Reference yield:

: 1761-61-1
5-bromosalicyclaldehyde

: 1314234-88-2
tert-butyl N-{[5-bromo-2-(prop-2-en-1-yloxy)phenyl](3,3-dimethylcycloprop-1-en-1-yl)methyl}carbamate

Guidance literature:: Multi-step reaction with 3 steps

1.1: potassium carbonate / N,N-dimethyl-formamide / 1.5 h / 20 °C

2.1: formic acid; sodium 4-methylbenzenesulfinate / methanol; water / 16 h / 40 °C

2.2: 15 h / Reflux

3.1: n-butyllithium / hexanes; diethyl ether / 1 h / -78 - -10 °C

3.2: 0.25 h / -50 - 20 °C

3.3: Saturated solution

With n-butyllithium; formic acid; potassium carbonate; sodium 4-methylbenzenesulfinate; In methanol; hexanes; diethyl ether; water; N,N-dimethyl-formamide;
DOI:10.1002/anie.201101220

Reference yield:

: 40359-62-4
2-allyloxy-5-bromobenzaldehyde

: 1314234-88-2
tert-butyl N-{[5-bromo-2-(prop-2-en-1-yloxy)phenyl](3,3-dimethylcycloprop-1-en-1-yl)methyl}carbamate

Guidance literature:: Multi-step reaction with 2 steps

1.1: formic acid; sodium 4-methylbenzenesulfinate / methanol; water / 16 h / 40 °C

1.2: 15 h / Reflux

2.1: n-butyllithium / hexanes; diethyl ether / 1 h / -78 - -10 °C

2.2: 0.25 h / -50 - 20 °C

2.3: Saturated solution

With n-butyllithium; formic acid; sodium 4-methylbenzenesulfinate; In methanol; hexanes; diethyl ether; water;
DOI:10.1002/anie.201101220