(+)-D-2,3,6-tris-O-benzyl-4-O-(methoxybenzyl)-myo-inositol 1,5-bis(dibenzyl phosphate)

Base Information

Chemical Name:(+)-D-2,3,6-tris-O-benzyl-4-O-(methoxybenzyl)-myo-inositol 1,5-bis(dibenzyl phosphate)
CAS No.:946419-51-8
Molecular Formula:C₆₃H₆₄O₁₃P₂
Molecular Weight:1091.14
Hs Code.:

Synonyms:(+)-D-2,3,6-tris-O-benzyl-4-O-(methoxybenzyl)-myo-inositol 1,5-bis(dibenzyl phosphate)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (+)-D-2,3,6-tris-O-benzyl-4-O-(methoxybenzyl)-myo-inositol 1,5-bis(dibenzyl phosphate)

Chemical Property:

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Technology Process of (+)-D-2,3,6-tris-O-benzyl-4-O-(methoxybenzyl)-myo-inositol 1,5-bis(dibenzyl phosphate)

There total 8 articles about (+)-D-2,3,6-tris-O-benzyl-4-O-(methoxybenzyl)-myo-inositol 1,5-bis(dibenzyl phosphate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₆₃H₆₄O₁₁P₂

: 946419-51-8
(+)-D-2,3,6-tris-O-benzyl-4-O-(methoxybenzyl)-myo-inositol 1,5-bis(dibenzyl phosphate)

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at -78 - 25 ℃;
DOI:10.1021/jo070611a

Reference yield:

: 946419-49-4
(+)-D-1,5-bis-O-allyl-2,3,6-tris-O-benzyl-4-O-(4-methoxybenzyl)-myo-inositol

: 946419-51-8
(+)-D-2,3,6-tris-O-benzyl-4-O-(methoxybenzyl)-myo-inositol 1,5-bis(dibenzyl phosphate)

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-BuLi / Rh(PPh₃)Cl / tetrahydrofuran; hexane / 6 h / Heating

1.2: 89 percent / acetyl chloride; methanol / CH₂Cl₂ / 3 h

2.1: 1H-tetrazole / CH₂Cl₂

3.1: 1.4 g / 3-chloro-peroxybenzoic acid / CH₂Cl₂ / -78 - 25 °C

With 1H-tetrazole; n-butyllithium; 3-chloro-benzenecarboperoxoic acid; Rh(PPh₃)Cl; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1021/jo070611a

Reference yield:

: 946419-42-7
(-)-D-1,5-bis-O-allyl-2,6-bis-O-benzyl-myo-inositol

: 946419-51-8
(+)-D-2,3,6-tris-O-benzyl-4-O-(methoxybenzyl)-myo-inositol 1,5-bis(dibenzyl phosphate)

Guidance literature:: Multi-step reaction with 5 steps

1.1: 71 percent / Bu₂SnO; nBu₄NI; molecular sieves 3 Angstroem / acetonitrile / 24 h / Heating

2.1: 95 percent / NaH; nBu₄NI / dimethylformamide / 0 - 25 °C

3.1: n-BuLi / Rh(PPh₃)Cl / tetrahydrofuran; hexane / 6 h / Heating

3.2: 89 percent / acetyl chloride; methanol / CH₂Cl₂ / 3 h

4.1: 1H-tetrazole / CH₂Cl₂

5.1: 1.4 g / 3-chloro-peroxybenzoic acid / CH₂Cl₂ / -78 - 25 °C

With 1H-tetrazole; n-butyllithium; 3 A molecular sieve; tetra-(n-butyl)ammonium iodide; sodium hydride; di(n-butyl)tin oxide; 3-chloro-benzenecarboperoxoic acid; Rh(PPh₃)Cl; In tetrahydrofuran; hexane; dichloromethane; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/jo070611a