Acetic acid (1R,2S,4S)-4-isopropenyl-1-methyl-2-phenylselanyl-cyclohexyl ester

Base Information

• Chemical Name: Acetic acid (1R,2S,4S)-4-isopropenyl-1-methyl-2-phenylselanyl-cyclohexyl ester
• CAS No.: 76338-32-4
• Molecular Formula: C₁₈H₂₄O₂Se
• Molecular Weight: 351.347
• Mol file: 76338-32-4.mol

Synonyms:Acetic acid (1R,2S,4S)-4-isopropenyl-1-methyl-2-phenylselanyl-cyclohexyl ester

Chemical Property of Acetic acid (1R,2S,4S)-4-isopropenyl-1-methyl-2-phenylselanyl-cyclohexyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Acetic acid (1R,2S,4S)-4-isopropenyl-1-methyl-2-phenylselanyl-cyclohexyl ester

There total 3 articles about Acetic acid (1R,2S,4S)-4-isopropenyl-1-methyl-2-phenylselanyl-cyclohexyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 36.0%

6-acetoxy-2-hydroxy-2,6-dimethyl-3-phenylseleno-octa-7-ene (76338-31-3) → Acetic acid (1R,2S,4S)-4-isopropenyl-1-methyl-2-phenylselanyl-cyclohexyl ester (76338-32-4) + Trifluoro-acetic acid 1-((1R,3R,4S)-4-acetoxy-4-methyl-3-phenylselanyl-cyclohexyl)-1-methyl-ethyl ester (76358-34-4)

Guidance literature:

With trifluoroacetic acid; In dichloromethane; at 0 ℃; for 0.5h;

DOI:10.1039/P19810000756

Reference yield:

1-(3,4-epoxy-4-methylpentyl)-1-methylallyl acetate (41610-76-8) → Acetic acid (1R,2S,4S)-4-isopropenyl-1-methyl-2-phenylselanyl-cyclohexyl ester (76338-32-4)

Guidance literature:

Multi-step reaction with 2 steps

2: 6.3 percent / CF₃COOH / CH₂Cl₂

With trifluoroacetic acid; In dichloromethane;

DOI:10.1039/c39800000762

Reference yield:

linalool acetate (115-95-7) → Acetic acid (1R,2S,4S)-4-isopropenyl-1-methyl-2-phenylselanyl-cyclohexyl ester (76338-32-4)

Guidance literature:

Multi-step reaction with 3 steps

1: m-chloroperbenzoic acid

3: 6.3 percent / CF₃COOH / CH₂Cl₂

With 3-chloro-benzenecarboperoxoic acid; trifluoroacetic acid; In dichloromethane;

DOI:10.1039/c39800000762

upstream raw materials:

6-acetoxy-2-hydroxy-2,6-dimethyl-3-phenylseleno-octa-7-ene

1-(3,4-epoxy-4-methylpentyl)-1-methylallyl acetate

linalool acetate

Downstream raw materials:

1α-hydroxy-2α-phenylseleno-trans-p-menth-8-ene

1-acetoxy-trans-p-mentha-2,8-diene