C₆₈H₈₇I₃O₆

Base Information

• Chemical Name: C₆₈H₈₇I₃O₆
• CAS No.: 702702-01-0
• Molecular Formula: C₆₈H₈₇I₃O₆
• Molecular Weight: 1381.15
• Mol file: 702702-01-0.mol

Synonyms:C₆₈H₈₇I₃O₆

Chemical Property of C₆₈H₈₇I₃O₆

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of C₆₈H₈₇I₃O₆

There total 1 articles about C₆₈H₈₇I₃O₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

1-(10-bromo-decyloxy)-4-iodo-benzene + 1,1,1-tris(4-hydroxyphenyl)ethane (27955-94-8) → C68H87I3O6 (702702-01-0)

Guidance literature:

With dibenzo-24-crown ether; caesium carbonate; In N,N-dimethyl-formamide; at 110 ℃; for 2h;

DOI:10.1021/ma035548f

Reference yield: 89.0%

C68H87I3O6 (702702-01-0) + trimethylsilylacetylene (1066-54-2) → C83H114O6Si3 (702702-03-2)

Guidance literature:

With triethylamine; triphenylphosphine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; In toluene; at 60 ℃; for 6h;

DOI:10.1021/ma035548f

Reference yield:

C68H87I3O6 (702702-01-0) → C74H90O6

Guidance literature:

Multi-step reaction with 2 steps

1: 89 percent / Et₃N; PPh₃ / Pd(PPh₃)2Cl₂; CuI / toluene / 6 h / 60 °C

2: 55 percent / K₂CO₃ / methanol; tetrahydrofuran / 1.5 h / 25 °C

With potassium carbonate; triethylamine; triphenylphosphine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; In tetrahydrofuran; methanol; toluene; 1: Sonogashira coupling;

DOI:10.1021/ma035548f

upstream raw materials:

1,1,1-tris(4-hydroxyphenyl)ethane

Downstream raw materials:

C₈₃H₁₁₄O₆Si₃