4,4'-(2-phenyl-1,3-dioxane-5,5-diyl)bis(methylene)bis(oxy)diphthalonitrile

Base Information

• Chemical Name: 4,4'-(2-phenyl-1,3-dioxane-5,5-diyl)bis(methylene)bis(oxy)diphthalonitrile
• CAS No.: 1011269-85-4
• Molecular Formula: C₂₈H₂₀N₄O₄
• Molecular Weight: 476.491
• Mol file: 1011269-85-4.mol

Synonyms:4,4'-(2-phenyl-1,3-dioxane-5,5-diyl)bis(methylene)bis(oxy)diphthalonitrile

Chemical Property of 4,4'-(2-phenyl-1,3-dioxane-5,5-diyl)bis(methylene)bis(oxy)diphthalonitrile

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4,4'-(2-phenyl-1,3-dioxane-5,5-diyl)bis(methylene)bis(oxy)diphthalonitrile

There total 1 articles about 4,4'-(2-phenyl-1,3-dioxane-5,5-diyl)bis(methylene)bis(oxy)diphthalonitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

5,5-dihydroxymethyl-2-phenyl-1,3-dioxane (2425-41-4) + 4-Nitrophthalonitrile (31643-49-9) → 4,4'-(2-phenyl-1,3-dioxane-5,5-diyl)bis(methylene)bis(oxy)diphthalonitrile (1011269-85-4)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; at 50 ℃; for 30h;

DOI:10.1002/ejic.200700141

Reference yield: 23.0%

4,4'-(2-phenyl-1,3-dioxane-5,5-diyl)bis(methylene)bis(oxy)diphthalonitrile (1011269-85-4) → 2',10',16',24'-[tetrakis(2-phenyl-1,3-dioxan-5,5-diyl)bis(methylene)bis(oxy)]bis(phthalocyaninato)dizinc(II)

Guidance literature:

With zinc diacetate; at 300 ℃; for 0.166667h;

DOI:10.1002/ejic.200700141

Reference yield: 23.0%

4,4'-(2-phenyl-1,3-dioxane-5,5-diyl)bis(methylene)bis(oxy)diphthalonitrile (1011269-85-4) + zinc(II) acetate dihydrate (5970-45-6) → 2',10',16',24'-[tetrakis(2-pheny-1,3-dioxan-5,5-diyl)bis(methylene)bis(oxy)]bis(phthalocyaninato)dizinc

Guidance literature:

In neat (no solvent); Ar, Zn:nitrile=1:0.5 molar ratio, ground, sealed, heated at 300.degre.C for 10 min; cooled to room temp., repptd. (DMF-acetone/ethanol), ppt. filtered, washed (water, ethanol, acetone), dried (vac.), chromy. (silica gel, THF/DMF); elem. anal.;

DOI:10.1002/ejic.200700141

upstream raw materials:

5,5-dihydroxymethyl-2-phenyl-1,3-dioxane

4-Nitrophthalonitrile