2-syn,3-syn,5-syn,6-syn-tetrakis<3'-<2''-formylphenyl>propoxymethyl>bicyclo<2.2.2>octane

Base Information

Chemical Name:2-syn,3-syn,5-syn,6-syn-tetrakis<3'-<2''-formylphenyl>propoxymethyl>bicyclo<2.2.2>octane
CAS No.:142483-77-0
Molecular Formula:C₅₂H₆₂O₈
Molecular Weight:815.059
Hs Code.:

Synonyms:2-syn,3-syn,5-syn,6-syn-tetrakis<3'-<2''-formylphenyl>propoxymethyl>bicyclo<2.2.2>octane

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Chemical Property of 2-syn,3-syn,5-syn,6-syn-tetrakis<3'-<2''-formylphenyl>propoxymethyl>bicyclo<2.2.2>octane

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Technology Process of 2-syn,3-syn,5-syn,6-syn-tetrakis<3'-<2''-formylphenyl>propoxymethyl>bicyclo<2.2.2>octane

There total 7 articles about 2-syn,3-syn,5-syn,6-syn-tetrakis<3'-<2''-formylphenyl>propoxymethyl>bicyclo<2.2.2>octane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 142483-76-9
2-syn,3-syn,5-syn,6-syn-tetrakis<3'-<2''-(1''',3'''-dioxolan-2'''-yl)phenyl>propoxymethyl>bicyclo<2.2.2>octane

: 142483-77-0
2-syn,3-syn,5-syn,6-syn-tetrakis<3'-<2''-formylphenyl>propoxymethyl>bicyclo<2.2.2>octane

Guidance literature:: With pyridinium p-toluenesulfonate; In water; acetone; for 16h; Heating;
DOI:10.1021/ja00043a003

Reference yield:

: 62234-70-2
tetraethyl bicyclo<2.2.2>oct-7-ene-2-syn,3-syn,5-syn,6-syn-tetracarboxylate

: 142483-77-0
2-syn,3-syn,5-syn,6-syn-tetrakis<3'-<2''-formylphenyl>propoxymethyl>bicyclo<2.2.2>octane

Guidance literature:: Multi-step reaction with 4 steps

1: 8 g / H₂ / 5percent Pd/C / ethyl acetate / 48 h / 760 Torr / Ambient temperature

2: 75 percent / LiAlH₄ / tetrahydrofuran / 16 h / Heating

3: 1.) KH, HMPA / 1.) 10 min, 2.) 50 deg C, 1 h

4: 87 percent / pyridinium p-tosylate / H₂O; acetone / 16 h / Heating

With N,N,N,N,N,N-hexamethylphosphoric triamide; lithium aluminium tetrahydride; hydrogen; pyridinium p-toluenesulfonate; potassium hydride; palladium on activated charcoal; In tetrahydrofuran; water; ethyl acetate; acetone;
DOI:10.1021/ja00043a003

Reference yield:

: 62234-72-4
2-syn,3-syn,5-syn,6-syn-tetrakis(hydroxymethyl)bicyclo<2.2.2>octane

: 142483-77-0
2-syn,3-syn,5-syn,6-syn-tetrakis<3'-<2''-formylphenyl>propoxymethyl>bicyclo<2.2.2>octane

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) KH, HMPA / 1.) 10 min, 2.) 50 deg C, 1 h

2: 87 percent / pyridinium p-tosylate / H₂O; acetone / 16 h / Heating

With N,N,N,N,N,N-hexamethylphosphoric triamide; pyridinium p-toluenesulfonate; potassium hydride; In water; acetone;
DOI:10.1021/ja00043a003