ethyl (1S)-1-((S)-1-((tert-butoxycarbonyl)amino)-1-phenylmethyl)-2-oxocyclopentanecarboxylate

Base Information

Chemical Name:ethyl (1S)-1-((S)-1-((tert-butoxycarbonyl)amino)-1-phenylmethyl)-2-oxocyclopentanecarboxylate
CAS No.:1232237-59-0
Molecular Formula:C₂₀H₂₇NO₅
Molecular Weight:361.438
Hs Code.:

Synonyms:ethyl (1S)-1-((S)-1-((tert-butoxycarbonyl)amino)-1-phenylmethyl)-2-oxocyclopentanecarboxylate

Suppliers and Price of ethyl (1S)-1-((S)-1-((tert-butoxycarbonyl)amino)-1-phenylmethyl)-2-oxocyclopentanecarboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of ethyl (1S)-1-((S)-1-((tert-butoxycarbonyl)amino)-1-phenylmethyl)-2-oxocyclopentanecarboxylate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of ethyl (1S)-1-((S)-1-((tert-butoxycarbonyl)amino)-1-phenylmethyl)-2-oxocyclopentanecarboxylate

There total 2 articles about ethyl (1S)-1-((S)-1-((tert-butoxycarbonyl)amino)-1-phenylmethyl)-2-oxocyclopentanecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 611-10-9
2-ethoxycarbonyl-1-cyclopentanone

: 150884-50-7
benzaldehyde N-boc imine

: 1232237-59-0
ethyl (1S)-1-((S)-1-((tert-butoxycarbonyl)amino)-1-phenylmethyl)-2-oxocyclopentanecarboxylate

Guidance literature:: With 1-((1S,2S)-2-(dimethylamino)cyclohexyl)-3-(((1R,4aS,10aR)-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octahydrophenanthren-1-yl)methyl)thiourea; In toluene; at -60 ℃; for 12.25h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1039/c000621a

Reference yield:

: 1355078-52-2
di(tert-butyl) N,N'-benzylidenebis(carbamate)

: 611-10-9
2-ethoxycarbonyl-1-cyclopentanone

: 1232237-59-0
ethyl (1S)-1-((S)-1-((tert-butoxycarbonyl)amino)-1-phenylmethyl)-2-oxocyclopentanecarboxylate

: ethyl 1-(1-((tert-butoxycarbonyl)amino)-1-phenylmethyl)-2-oxocyclopentanecarboxylate

Guidance literature:: With C₅₆H₃₃F₄O₄P; In dichloromethane; at 20 ℃; for 36h; Overall yield = 97 %; Overall yield = 37 mg; enantioselective reaction; Molecular sieve;
DOI:10.1002/anie.201304963