5-(4-methoxyphenyl)-2-(3-(4-methoxyphenyl)-5-oxocyclohexyl)cyclohex-2-enone

Base Information

Chemical Name:5-(4-methoxyphenyl)-2-(3-(4-methoxyphenyl)-5-oxocyclohexyl)cyclohex-2-enone
CAS No.:1360468-59-2
Molecular Formula:C₂₆H₂₈O₄
Molecular Weight:404.506
Hs Code.:

Synonyms:5-(4-methoxyphenyl)-2-(3-(4-methoxyphenyl)-5-oxocyclohexyl)cyclohex-2-enone

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Chemical Property of 5-(4-methoxyphenyl)-2-(3-(4-methoxyphenyl)-5-oxocyclohexyl)cyclohex-2-enone

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Technology Process of 5-(4-methoxyphenyl)-2-(3-(4-methoxyphenyl)-5-oxocyclohexyl)cyclohex-2-enone

There total 3 articles about 5-(4-methoxyphenyl)-2-(3-(4-methoxyphenyl)-5-oxocyclohexyl)cyclohex-2-enone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 117825-94-2
5-(4-methoxyphenyl)cyclohex-2-enone

: 1360468-59-2
5-(4-methoxyphenyl)-2-(3-(4-methoxyphenyl)-5-oxocyclohexyl)cyclohex-2-enone

Guidance literature:: With bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; potassium hydroxide; In 1,4-dioxane; water; at 90 ℃; for 2h; regioselective reaction; Inert atmosphere;
DOI:10.1016/j.tetlet.2011.12.057

Reference yield:

: 1963-36-6
4-methoxycinnamaldehyde

: 1360468-59-2
5-(4-methoxyphenyl)-2-(3-(4-methoxyphenyl)-5-oxocyclohexyl)cyclohex-2-enone

Guidance literature:: Multi-step reaction with 3 steps

1: (2S)-2-{diphenyl[(trimethylsilyl)oxy]methyl}pyrrolidine; 1,4-diaza-bicyclo[2.2.2]octane; lithium perchlorate / chloroform / 20 °C

2: water; lithium chloride / dimethyl sulfoxide

3: bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; potassium hydroxide / 1,4-dioxane; water / 2 h / 90 °C / Inert atmosphere

With (2S)-2-{diphenyl[(trimethylsilyl)oxy]methyl}pyrrolidine; 1,4-diaza-bicyclo[2.2.2]octane; bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; water; lithium perchlorate; lithium chloride; potassium hydroxide; In 1,4-dioxane; chloroform; water; dimethyl sulfoxide; 3: Michael condensation;
DOI:10.1016/j.tetlet.2011.12.057

Reference yield:

: 6-(4-Methoxy-phenyl)-2-oxo-cyclohex-3-enecarboxylic acid ethyl ester

: 1360468-59-2
5-(4-methoxyphenyl)-2-(3-(4-methoxyphenyl)-5-oxocyclohexyl)cyclohex-2-enone

Guidance literature:: Multi-step reaction with 2 steps

1: water; lithium chloride / dimethyl sulfoxide

2: bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; potassium hydroxide / 1,4-dioxane; water / 2 h / 90 °C / Inert atmosphere

With bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; water; lithium chloride; potassium hydroxide; In 1,4-dioxane; water; dimethyl sulfoxide; 2: Michael condensation;
DOI:10.1016/j.tetlet.2011.12.057