[Au(1,3-bis(2,6-bis(di-p-tolylmethyl)-4-methylphenyl)imidazol-2-ylidene)(Cl)]

Base Information

• Chemical Name: [Au(1,3-bis(2,6-bis(di-p-tolylmethyl)-4-methylphenyl)imidazol-2-ylidene)(Cl)]
• CAS No.: 1439915-47-5
• Molecular Formula: C₇₇H₇₂AuClN₂
• Molecular Weight: 1257.85
• Mol file: 1439915-47-5.mol

Synonyms:[Au(1,3-bis(2,6-bis(di-p-tolylmethyl)-4-methylphenyl)imidazol-2-ylidene)(Cl)]

Chemical Property of [Au(1,3-bis(2,6-bis(di-p-tolylmethyl)-4-methylphenyl)imidazol-2-ylidene)(Cl)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Au(1,3-bis(2,6-bis(di-p-tolylmethyl)-4-methylphenyl)imidazol-2-ylidene)(Cl)]

There total 1 articles about [Au(1,3-bis(2,6-bis(di-p-tolylmethyl)-4-methylphenyl)imidazol-2-ylidene)(Cl)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

1,3-bis(2,6-bis(di-p-tolylmethyl)-4-methylphenyl)imidazolium chloride (1421841-85-1) → [Au(1,3-bis(2,6-bis(di-p-tolylmethyl)-4-methylphenyl)imidazol-2-ylidene)(Cl)] (1439915-47-5)

Guidance literature:

With dimethylsulfide gold(I) chloride; potassium carbonate; In acetone; at 60 ℃; for 2h;

DOI:10.1039/c3cc43076f

Reference yield: 83.0%

[Au(1,3-bis(2,6-bis(di-p-tolylmethyl)-4-methylphenyl)imidazol-2-ylidene)(Cl)] (1439915-47-5) + sodium hydroxide (1310-73-2) → [Au(1,3-bis(2,6-bis(di-p-tolylmethyl)-4-methylphenyl)imidazol-2-ylidene)(OH)]

Guidance literature:

With tert-Amyl alcohol; In tetrahydrofuran; at 20 ℃; for 24h;

DOI:10.1016/j.poly.2014.06.017

Reference yield: 80.0%

[Au(1,3-bis(2,6-bis(di-p-tolylmethyl)-4-methylphenyl)imidazol-2-ylidene)(Cl)] (1439915-47-5) + potassium hydroxide → [Au(1,3-bis(2,6-bis(di-p-tolylmethyl)-4-methylphenyl)imidazol-2-ylidene)(OH)]

Guidance literature:

In tetrahydrofuran; at 30 ℃; for 20h;

DOI:10.1021/om4010065

upstream raw materials:

1,3-bis(2,6-bis(di-p-tolylmethyl)-4-methylphenyl)imidazolium chloride