(2,6-(CHMe₂)2C₆H₃NC(tBu)CHC(tBu)NC₆H₃(CHMe₂)2-2,6)Zr(CH₂tBu)2Cl

Base Information

• Chemical Name: (2,6-(CHMe₂)2C₆H₃NC(tBu)CHC(tBu)NC₆H₃(CHMe₂)2-2,6)Zr(CH₂tBu)2Cl
• CAS No.: 827342-29-0
• Molecular Formula: C₄₅H₇₅ClN₂Zr
• Molecular Weight: 770.781
• Mol file: 827342-29-0.mol

Synonyms:(2,6-(CHMe₂)2C₆H₃NC(tBu)CHC(tBu)NC₆H₃(CHMe₂)2-2,6)Zr(CH₂tBu)2Cl

Chemical Property of (2,6-(CHMe₂)2C₆H₃NC(tBu)CHC(tBu)NC₆H₃(CHMe₂)2-2,6)Zr(CH₂tBu)2Cl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2,6-(CHMe₂)2C₆H₃NC(tBu)CHC(tBu)NC₆H₃(CHMe₂)2-2,6)Zr(CH₂tBu)2Cl

There total 2 articles about (2,6-(CHMe₂)2C₆H₃NC(tBu)CHC(tBu)NC₆H₃(CHMe₂)2-2,6)Zr(CH₂tBu)2Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

(2,6-(CHMe2)2C6H3NC(tBu)CHC(tBu)NC6H3(CHMe2)2-2,6)ZrCl3 (827342-27-8) + neopentyl lithium (7412-67-1) → (2,6-(CHMe2)2C6H3NC(tBu)CHC(tBu)NC6H3(CHMe2)2-2,6)Zr(CH2tBu)2Cl (827342-29-0)

Guidance literature:

In diethyl ether; under inert atm. to suspn. Zr complex in Et2O at -35°C soln. LiCH2CMe3 in Et2O was added and stirred for 30 min; soln. was filtered, filtrate was concd. and stored at -35°C for 24 h; elem. anal.;

DOI:10.1021/om049332t

Reference yield:

Li[((C6H3(CH(CH3)2)2-2,6)NC(t-Bu)CHC(t-Bu)N(C6H3(CH(CH3)2)2-2,6)] → (2,6-(CHMe2)2C6H3NC(tBu)CHC(tBu)NC6H3(CHMe2)2-2,6)Zr(CH2tBu)2Cl (827342-29-0)

Guidance literature:

Multi-step reaction with 2 steps

1: toluene

2: diethyl ether

In diethyl ether; toluene;

DOI:10.1021/om049332t

Reference yield:

diethyl ether (60-29-7,927820-24-4) + (2,6-(CHMe2)2C6H3NC(tBu)CHC(tBu)NC6H3(CHMe2)2-2,6)Zr(CH2tBu)2Cl (827342-29-0) → (2,6-(CHMe2)2C6H3NC(tBu)CHC(tBu)NC6H3(CHMe2)2-2,6)Zr(CH2tBu)2Cl*1/2Et2O

Guidance literature:

In diethyl ether; pentane;

DOI:10.1021/om049332t

upstream raw materials:

(2,6-(CHMe₂)2C₆H₃NC(tBu)CHC(tBu)NC₆H₃(CHMe₂)2-2,6)ZrCl₃

neopentyl lithium