1,3-Cyclohexadiene,5-[(1R)-1,5-dimethyl-4-hexen-1-yl]-2-methyl-, (5R)-

Base Information

• Chemical Name: 1,3-Cyclohexadiene,5-[(1R)-1,5-dimethyl-4-hexen-1-yl]-2-methyl-, (5R)-
• CAS No.: 158848-19-2
• Molecular Formula: C15H24
• Molecular Weight: 204.356
• Mol file: 158848-19-2.mol

Synonyms:1,3-Cyclohexadiene,5-(1,5-dimethyl-4-hexenyl)-2-methyl-, [R-(R*,R*)]-; 1,3-Cyclohexadiene, 5-[(1R)-1,5-dimethyl-4-hexenyl]-2-methyl-,(5R)- (9CI); 7-Epizingiberene; 7-epi-Zingiberene

Chemical Property of 1,3-Cyclohexadiene,5-[(1R)-1,5-dimethyl-4-hexen-1-yl]-2-methyl-, (5R)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,3-Cyclohexadiene,5-[(1R)-1,5-dimethyl-4-hexen-1-yl]-2-methyl-, (5R)-

There total 10 articles about 1,3-Cyclohexadiene,5-[(1R)-1,5-dimethyl-4-hexen-1-yl]-2-methyl-, (5R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

(3S,6R,7R)-1,10-bisaboladien-3-ol (72346-47-5) → (6R,7R)-(-)-1,3(15),10-bisabolatriene + (6S,7R)-1,3,10-bisabolatriene (158848-19-2)

Guidance literature:

With pyridine; trichlorophosphate; at 0 - 25 ℃;

DOI:10.1021/np5003753

Reference yield:

(3R,6R,7R)-1,10-bisaboladien-3-ol (72346-46-4) → (6R,7R)-(-)-1,3(15),10-bisabolatriene + (6S,7R)-1,3,10-bisabolatriene (158848-19-2)

Guidance literature:

With pyridine; trichlorophosphate; at 0 - 20 ℃; for 2h; Overall yield = 53 mg;

Reference yield:

dimethylallyl diphosphate (358-72-5) + isopentyl pyrophosphate (358-71-4) → (6S,7R)-1,3,10-bisabolatriene (158848-19-2)

Guidance literature:

With 1,4-dithio-L-threitol; (2Z,6Z)-FDP synthase from Solanum habrochaites; 7-epizingiberene synthase from Solanum habrochaites; magnesium chloride; In aq. buffer; at 20 ℃; for 16h; pH=8; Enzymatic reaction;

DOI:10.1002/anie.202001744

upstream raw materials:

methylmagnesium bromide

4-[(1R)-1,5-dimethylhex-4-enyl]cyclohex-2-en-1-one

(3R,6R,7R)-1,10-bisaboladien-3-ol

(3S,6R,7R)-1,10-bisaboladien-3-ol

Downstream raw materials:

(R)-(-)-α-curcumene

biyouyanagin C

C₃₁H₃₈O₄

C₃₁H₃₈O₄