NiCl(C₆H₅B(CH₂P(C₆H₅)2)3)

Base Information

• Chemical Name: NiCl(C₆H₅B(CH₂P(C₆H₅)2)3)
• CAS No.: 741735-75-1
• Molecular Formula: C₄₅H₄₁BClNiP₃
• Molecular Weight: 779.696
• Mol file: 741735-75-1.mol

Synonyms:NiCl(C₆H₅B(CH₂P(C₆H₅)2)3)

Chemical Property of NiCl(C₆H₅B(CH₂P(C₆H₅)2)3)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of NiCl(C₆H₅B(CH₂P(C₆H₅)2)3)

There total 1 articles about NiCl(C₆H₅B(CH₂P(C₆H₅)2)3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

bis(triphenylphosphine)nickel(II) chloride (14264-16-5,53996-95-5,62075-39-2,39716-73-9) + tallium (diphenylphosphinomethyl)phenylborate (388110-49-4) → NiCl(C6H5B(CH2P(C6H5)2)3) (741735-75-1)

Guidance literature:

In benzene; byproducts: TlCl; under N2; benzene soln. of Tl-complex was added dropwise to suspn. of Ni-complex in benzene, stirred at room temp. for 24 h; filtered, concd. under reduced pressure, washed with petroleum ether, redissolved in benzene, filtered, vapor diffusion of petroleum ether; elem. anal.;

DOI:10.1021/ic049936p

Reference yield: 95.0%

NiCl(C6H5B(CH2P(C6H5)2)3) (741735-75-1) + triphenylphosphine (603-35-0) → Ni(C6H5B(CH2P(C6H5)2)3)P(C6H5)3

Guidance literature:

With KC₈; In tetrahydrofuran; under N2; PPh3 was added to stirred soln. of Ni-complex in THF, THF soln. of KC8 was added, stirred for 12 h; volaties were removed under reduced pressure, extd. with benzene, filtered, petroleum ether was slow diffused into filtrate; elme. anal.;

DOI:10.1021/ic049936p

Reference yield: 94.0%

NiCl(C6H5B(CH2P(C6H5)2)3) (741735-75-1) + oxygen (80937-33-3) + toluene (108-88-3,15644-74-3,16713-13-6) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → [NiCl[(C6H5B(CH2PO(C6H5)2)2)(CH2P(C6H5)2)]]2*2C7H8*C6H6*CH2Cl2

Guidance literature:

In benzene; soln. of Ni-complex in benzene was treated with O2, stirred at room temp. for 6 h; volatiles were removed under reduced pressure, extd. into benzene, filtered, petroleum ether was slow diffused into benzene soln. at room temp.;elem. anal.;

DOI:10.1021/ic049936p

upstream raw materials:

bis(triphenylphosphine)nickel(II) chloride

tallium (diphenylphosphinomethyl)phenylborate

Downstream raw materials:

Ni(N₃)(C₆H₅B(CH₂P(C₆H₅)2)3)

NiI(C₆H₅B(CH₂P(C₆H₅)2)3)

Ni(C₆H₅B(CH₂P(C₆H₅)2)3)CN(C(CH₃)3)

NiCl[(C₆H₅B(CH₂PO(C₆H₅)2)2)(CH₂P(C₆H₅)2)]