η2-(η4-cyclooctadiene)(η2-bromophenyl(diphenylphosphine))iridium(I) hexafluoroantimonate

Base Information

Chemical Name:η2-(η4-cyclooctadiene)(η2-bromophenyl(diphenylphosphine))iridium(I) hexafluoroantimonate
CAS No.:89232-37-1
Molecular Formula:C₂₆H₂₆BrIrP*F₆Sb
Molecular Weight:877.331
Hs Code.:

Synonyms:η2-(η4-cyclooctadiene)(η2-bromophenyl(diphenylphosphine))iridium(I) hexafluoroantimonate

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Chemical Property of η2-(η4-cyclooctadiene)(η2-bromophenyl(diphenylphosphine))iridium(I) hexafluoroantimonate

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Technology Process of η2-(η4-cyclooctadiene)(η2-bromophenyl(diphenylphosphine))iridium(I) hexafluoroantimonate

There total 4 articles about η2-(η4-cyclooctadiene)(η2-bromophenyl(diphenylphosphine))iridium(I) hexafluoroantimonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 26042-64-8
silver hexafluoroantimonate

: 89232-35-9
{Ir(1,5-cyclooctadiene)(η1-(o-bromophenyl)diphenylphosphine)Cl}

: 89232-37-1
{Ir(1,5-cyclooctadiene)(η2-(o-bromophenyl)diphenylphosphine)}SbF6

Guidance literature:: In dichloromethane; Ir-complex was treated with AgSbF6 at 20°C in CH2Cl2; soln. was filtered through Celite, Et2O added, ppt. collected; identified by (1)H and (31)P NMR spectra and by X-ray study;

Reference yield:

: {IrMe(cod)(η1-o-BrC6H4PPh2)}

: 89232-37-1
η2-(η4-cyclooctadiene)(η2-bromophenyl(diphenylphosphine))iridium(I) hexafluoroantimonate

Guidance literature:: With HBF₄*Et₂O; In benzene; byproducts: CH4; addn. of HBF4*Et2O to {IrMe(cod)(η1-o-BrC6H4PPh2)}, soln. turning colour from red to orange, pptn. after 3 min; filtration after 15 min, washing with pentane (three times), drying in vacuo;
DOI:10.1016/0022-328X(88)89103-4

Reference yield:

: 89232-35-9
{Ir(cod)Cl(μ1-o-C6H4(Br)PPh2)}

: 89232-37-1
η2-(η4-cyclooctadiene)(η2-bromophenyl(diphenylphosphine))iridium(I) hexafluoroantimonate

Guidance literature:: With AgSbF₆; In dichloromethane; treating of {IrCl(cod)(BrC6H4(PPh2))} with AgSbF6 in CH2Cl2, stirring for 20 min in the dark; filterting through Celite, concg., addn. of ether, pptn., elem. anal.;
DOI:10.1016/0022-328X(88)89103-4