methyl (5S)-2,2-dimethyl-4,5,6,6a-tetrahydro-3aH-cyclopenta[d][1,3]dioxole-5-carboxylate

Base Information

Chemical Name:methyl (5S)-2,2-dimethyl-4,5,6,6a-tetrahydro-3aH-cyclopenta[d][1,3]dioxole-5-carboxylate
CAS No.:39798-12-4
Molecular Formula:C₁₀H₁₆O₄
Molecular Weight:200.235
Hs Code.:

Synonyms:methyl (5S)-2,2-dimethyl-4,5,6,6a-tetrahydro-3aH-cyclopenta[d][1,3]dioxole-5-carboxylate

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Chemical Property of methyl (5S)-2,2-dimethyl-4,5,6,6a-tetrahydro-3aH-cyclopenta[d][1,3]dioxole-5-carboxylate

Chemical Property:

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Technology Process of methyl (5S)-2,2-dimethyl-4,5,6,6a-tetrahydro-3aH-cyclopenta[d][1,3]dioxole-5-carboxylate

There total 2 articles about methyl (5S)-2,2-dimethyl-4,5,6,6a-tetrahydro-3aH-cyclopenta[d][1,3]dioxole-5-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 58101-60-3
methyl cyclopent-3-ene-1-carboxylate

: 39798-12-4,77714-60-4
methyl 6t-cis-2,2-dimethyl-1,3-dioxabicyclo<3.3.0>octanecarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: osmium tetraoxide, N-methylmorpholine N-oxide / 2-methyl-propan-2-ol; H₂O / 4 h / Ambient temperature

2: Amberlyst-15 / acetone / 6 h / Ambient temperature

With osmium(VIII) oxide; amberlyst-15; 4-methylmorpholine N-oxide; In water; acetone; tert-butyl alcohol;
DOI:10.1021/ja00175a031

Reference yield:

: 58101-60-3
methyl cyclopent-3-ene-1-carboxylate

: 39798-12-4
methyl (5S)-2,2-dimethyl-4,5,6,6a-tetrahydro-3aH-cyclopenta[d][1,3]dioxole-5-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 4-methylmorpholine N-oxide; osmium(VIII) oxide; Quinuclidine / acetone; water / 24 h

2: toluene-4-sulfonic acid / 1 h

With Quinuclidine; osmium(VIII) oxide; toluene-4-sulfonic acid; 4-methylmorpholine N-oxide; In water; acetone;

Reference yield:

: 39798-12-4
methyl (5S)-2,2-dimethyl-4,5,6,6a-tetrahydro-3aH-cyclopenta[d][1,3]dioxole-5-carboxylate

: 77714-63-7
4-(benzyloxymethyl)cyclopentane-cis-1,2-diol

Guidance literature:: Multi-step reaction with 3 steps

1: 95 percent / LiAlH₄ / tetrahydrofuran / Ambient temperature

2: 1) NaH / 1) DMF; 2) 2h 0 deg C, then room temp.

3: 87 percent / conc. aq. HCl / tetrahydrofuran; H₂O / 96 h

With hydrogenchloride; lithium aluminium tetrahydride; sodium hydride; In tetrahydrofuran; water;
DOI:10.1021/jo00329a011