Zn₂H₂((2,4,6-Me₃C₆H₂)NC(Me))2CH)2

Base Information

• Chemical Name: Zn₂H₂((2,4,6-Me₃C₆H₂)NC(Me))2CH)2
• CAS No.: 1234094-51-9
• Molecular Formula: C₄₆H₆₀N₄Zn₂
• Molecular Weight: 799.789
• Mol file: 1234094-51-9.mol

Synonyms:Zn₂H₂((2,4,6-Me₃C₆H₂)NC(Me))2CH)2

Chemical Property of Zn₂H₂((2,4,6-Me₃C₆H₂)NC(Me))2CH)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Zn₂H₂((2,4,6-Me₃C₆H₂)NC(Me))2CH)2

There total 2 articles about Zn₂H₂((2,4,6-Me₃C₆H₂)NC(Me))2CH)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

[(MesNacnac)ZnI] + KNH(iPr)BH3 → Zn2H2((2,4,6-Me3C6H2)NC(Me))2CH)2 (1234094-51-9)

Guidance literature:

In tetrahydrofuran; THF soln. of KNH(iPr)BH3 added to THF soln. of Zn deriv.; stirred for 2 h at ambient temp.; vac. evapn.; dissolved in toluene; filtered; crystd. at -30°C within 48 h; elem. anal.;

DOI:10.1515/znb-2009-11-1221

Reference yield: 43.0%

[(2,4,6-Me3-C6H2)NC(Me)]2CHZnCl + sodium hydride (7646-69-7) → Zn2H2((2,4,6-Me3C6H2)NC(Me))2CH)2 (1234094-51-9)

Guidance literature:

In tetrahydrofuran; THF suspn. of NaH, Zn deriv. stirred at ambient temp. for 3 d; vac. evapn.; dissolved in toluene; filtered; concd.; crystd. at -30°C within 48 h; elem. anal.;

DOI:10.1515/znb-2009-11-1221

Reference yield: 99.0%

Zn2H2((2,4,6-Me3C6H2)NC(Me))2CH)2 (1234094-51-9) + diisopropyl-carbodiimide (693-13-0) → ((CH3)3C6H2NC(CH3))2CHZn(CH(CH3)2N)2CH (1254961-20-0)

Guidance literature:

In neat (no solvent); Zn complex reacted with (iPr2N)2C at ambient temp. and normal pressure;

DOI:10.1039/c0cc01329c

upstream raw materials:

sodium hydride

Downstream raw materials:

((CH₃)3C₆H₂NC(CH₃))2CHZn(CH(CH₃)2N)2CH

(((CH₃)3C₆H₂NC(CH₃))2CHZn)2(CHOO)(COOH)

Zn(tBuNCHNtBu)[(2,4,6-Me₃C₆H₂)NC(Me)]2CH)

Zn₂(N₃)2[(2,4,6-Me₃C₆H₂)NC(Me)]2CH)2