1-[(1S,2R)-1-(3-Benzyloxy-propyl)-2-methyl-but-3-enyloxymethyl]-4-methoxy-benzene

Base Information

Chemical Name:1-[(1S,2R)-1-(3-Benzyloxy-propyl)-2-methyl-but-3-enyloxymethyl]-4-methoxy-benzene
CAS No.:330573-56-3
Molecular Formula:C₂₃H₃₀O₃
Molecular Weight:354.489
Hs Code.:

Synonyms:1-[(1S,2R)-1-(3-Benzyloxy-propyl)-2-methyl-but-3-enyloxymethyl]-4-methoxy-benzene

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Chemical Property of 1-[(1S,2R)-1-(3-Benzyloxy-propyl)-2-methyl-but-3-enyloxymethyl]-4-methoxy-benzene

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Technology Process of 1-[(1S,2R)-1-(3-Benzyloxy-propyl)-2-methyl-but-3-enyloxymethyl]-4-methoxy-benzene

There total 2 articles about 1-[(1S,2R)-1-(3-Benzyloxy-propyl)-2-methyl-but-3-enyloxymethyl]-4-methoxy-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 824-94-2
p-methoxybenzyl chloride

: 330573-57-4
(3R,4S)-7-Benzyloxy-3-methyl-hept-1-en-4-ol

: 330573-56-3
1-[(1S,2R)-1-(3-Benzyloxy-propyl)-2-methyl-but-3-enyloxymethyl]-4-methoxy-benzene

Guidance literature:: (3R,4S)-7-Benzyloxy-3-methyl-hept-1-en-4-ol; With tetra-(n-butyl)ammonium iodide; sodium hydride; In N,N-dimethyl-formamide; at 0 ℃; for 0.5h;

p-methoxybenzyl chloride; In N,N-dimethyl-formamide; at 0 - 20 ℃; Further stages.;
DOI:10.1021/ja004154q

Reference yield:

: 5470-84-8
4-benzyloxybutanal

: 330573-56-3
1-[(1S,2R)-1-(3-Benzyloxy-propyl)-2-methyl-but-3-enyloxymethyl]-4-methoxy-benzene

Guidance literature:: Multi-step reaction with 2 steps

1.1: potassium tert-butoxide; n-BuLi / tetrahydrofuran; hexane / 0.17 h / -45 °C

1.2: (+)-methoxydiisopinocampheylborane / tetrahydrofuran; hexane; diethyl ether / 0.5 h / -78 °C

1.3: boron trifluoride etherate / tetrahydrofuran; hexane; diethyl ether / 3 h / -78 °C

2.1: tetrabutylammonium iodide; NaH / dimethylformamide; various solvent(s) / 0.5 h / 0 °C

2.2: 91 percent / dimethylformamide; various solvent(s) / 0 - 20 °C

With n-butyllithium; potassium tert-butylate; tetra-(n-butyl)ammonium iodide; sodium hydride; In tetrahydrofuran; hexane; N,N-dimethyl-formamide; 1.1: Brown crotylboration / 1.2: Brown crotylboration / 1.3: Brown crotylboration;
DOI:10.1021/ja004154q