methyl 3-<3,4-dihydroxy-5-(4-hydroxycinnamoyl)-2-methoxy-3-methyl-6-oxo-1,4-cyclohexadienyl>-3-(4-hydroxyphenyl)propanoate

Base Information

Chemical Name:methyl 3-<3,4-dihydroxy-5-(4-hydroxycinnamoyl)-2-methoxy-3-methyl-6-oxo-1,4-cyclohexadienyl>-3-(4-hydroxyphenyl)propanoate
CAS No.:140170-49-6
Molecular Formula:C₂₇H₂₆O₉
Molecular Weight:494.498
Hs Code.:

Synonyms:methyl 3-<3,4-dihydroxy-5-(4-hydroxycinnamoyl)-2-methoxy-3-methyl-6-oxo-1,4-cyclohexadienyl>-3-(4-hydroxyphenyl)propanoate

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Chemical Property of methyl 3-<3,4-dihydroxy-5-(4-hydroxycinnamoyl)-2-methoxy-3-methyl-6-oxo-1,4-cyclohexadienyl>-3-(4-hydroxyphenyl)propanoate

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Technology Process of methyl 3-<3,4-dihydroxy-5-(4-hydroxycinnamoyl)-2-methoxy-3-methyl-6-oxo-1,4-cyclohexadienyl>-3-(4-hydroxyphenyl)propanoate

There total 4 articles about methyl 3-<3,4-dihydroxy-5-(4-hydroxycinnamoyl)-2-methoxy-3-methyl-6-oxo-1,4-cyclohexadienyl>-3-(4-hydroxyphenyl)propanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

: 123-08-0,65581-83-1
4-hydroxy-benzaldehyde

: 140170-48-5
methyl 3-(5-acetyl-3,4-dihydroxy-2-methoxy-3-methyl-6-oxo-1,4-cyclohexadienyl)-3-(4-hydroxyphenyl)propanoate

: 140170-50-9
methyl 3-<2,3,4-trihydroxy-5-(4-hydroxycinnamoyl)-3-methyl-6-oxo-1,4-cyclohexadienyl>-3-(4-hydroxyphenyl)propanoate

: 140170-49-6
methyl 3-<3,4-dihydroxy-5-(4-hydroxycinnamoyl)-2-methoxy-3-methyl-6-oxo-1,4-cyclohexadienyl>-3-(4-hydroxyphenyl)propanoate

Guidance literature:: With piperidine; at 85 ℃; for 1.5h;
DOI:10.1246/bcsj.65.452

Reference yield:

: 2657-28-5
2,4,6-trihydroxy-3-methyl-acetophenon

: 140170-49-6
methyl 3-<3,4-dihydroxy-5-(4-hydroxycinnamoyl)-2-methoxy-3-methyl-6-oxo-1,4-cyclohexadienyl>-3-(4-hydroxyphenyl)propanoate

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) 85percent H₃PO₄, 2.) lead(II) acetate trihydrate, O₂ / 1.) RT, 2.5 d, 2.) RT, 2.5 d

2: 96 percent / diethyl ether

3: 20 percent / piperidine / 1.5 h / 85 °C

With piperidine; phosphoric acid; oxygen; lead acetate; In diethyl ether;
DOI:10.1246/bcsj.65.452

Reference yield:

: 62018-55-7
3'-formyl-2',4',6'-trihydroxyacetophenone

: 140170-49-6
methyl 3-<3,4-dihydroxy-5-(4-hydroxycinnamoyl)-2-methoxy-3-methyl-6-oxo-1,4-cyclohexadienyl>-3-(4-hydroxyphenyl)propanoate

Guidance literature:: Multi-step reaction with 4 steps

1: concd HCl, zinc amalgam / H₂O; methanol / 0.25 h / 50 °C

2: 1.) 85percent H₃PO₄, 2.) lead(II) acetate trihydrate, O₂ / 1.) RT, 2.5 d, 2.) RT, 2.5 d

3: 96 percent / diethyl ether

4: 20 percent / piperidine / 1.5 h / 85 °C

With piperidine; hydrogenchloride; amalgamated zinc; phosphoric acid; oxygen; lead acetate; In methanol; diethyl ether; water;
DOI:10.1246/bcsj.65.452