closo-6-Me₂S-4-OH-2-{(Me₃Si)2CH}-CB₁₀H₈

Base Information

• Chemical Name: closo-6-Me₂S-4-OH-2-{(Me₃Si)2CH}-CB₁₀H₈
• CAS No.: 105399-70-0
• Molecular Formula: C₁₀H₃₄B₁₀OSSi₂
• Molecular Weight: 366.726
• Mol file: 105399-70-0.mol

Synonyms:closo-6-Me₂S-4-OH-2-{(Me₃Si)2CH}-CB₁₀H₈

Chemical Property of closo-6-Me₂S-4-OH-2-{(Me₃Si)2CH}-CB₁₀H₈

Chemical Property:

Purity/Quality:

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Technology Process of closo-6-Me₂S-4-OH-2-{(Me₃Si)2CH}-CB₁₀H₈

There total 1 articles about closo-6-Me₂S-4-OH-2-{(Me₃Si)2CH}-CB₁₀H₈ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.5%

9-(dimethyl sulfide)-7-{bis(trimethylsilyl)methyl}CB10H11 (105335-10-2) → closo-6-Me2S-4-OH-2-{(Me3Si)2CH}-CB10H8 (105399-70-0) + closo-6-Me2S-2-{(Me3Si)2CH}-CB10H9 (105335-13-5) + dimethylsulfide (75-18-3)

Guidance literature:

In neat (no solvent); evacuated tube containing carborane was heated at 100°C for 1 h and at 140°C for 1 h while pumping through a -196°C trap; Me2S condensed in the trap; glassy yellow solid at the base of the tube was extd. with CH2Cl2, ext. septd. by preparative TLC (SiO2, eluant benzene-hexane (1:1)); several unidentified compounds were also present;

DOI:10.1021/om00144a016

upstream raw materials:

9-(dimethyl sulfide)-7-{bis(trimethylsilyl)methyl}CB₁₀H₁₁