chloro{3,6-di-tert-butyl-1,8-bis-((diphenylphosphino)methyl)carbazole}palladium(II)

Base Information

Chemical Name:chloro{3,6-di-tert-butyl-1,8-bis-((diphenylphosphino)methyl)carbazole}palladium(II)
CAS No.:1421060-73-2
Molecular Formula:C₄₆H₄₆ClNP₂Pd
Molecular Weight:816.698
Hs Code.:

Synonyms:chloro{3,6-di-tert-butyl-1,8-bis-((diphenylphosphino)methyl)carbazole}palladium(II)

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Chemical Property of chloro{3,6-di-tert-butyl-1,8-bis-((diphenylphosphino)methyl)carbazole}palladium(II)

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Technology Process of chloro{3,6-di-tert-butyl-1,8-bis-((diphenylphosphino)methyl)carbazole}palladium(II)

There total 6 articles about chloro{3,6-di-tert-butyl-1,8-bis-((diphenylphosphino)methyl)carbazole}palladium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 12107-56-1
dichloro(1,5-cyclooctadiene)palladium(II)

: 1421060-70-9
3,6-di-tert-butyl-1,8-bis-((diphenylphosphino)methyl)-9H-carbazole

: 1421060-73-2
chloro{3,6-di-tert-butyl-1,8-bis-((diphenylphosphino)methyl)carbazole}palladium(II)

Guidance literature:: 3,6-di-tert-butyl-1,8-bis-((diphenylphosphino)methyl)-9H-carbazole; With lithium diisopropyl amide; In tetrahydrofuran; at 20 ℃; for 1h; Inert atmosphere;

dichloro(1,5-cyclooctadiene)palladium(II); In tetrahydrofuran; Inert atmosphere;
DOI:10.1021/ic302454n

Reference yield:

: 625385-37-7
1,8-dibromo-3,6-di(tert-butyl)-9H-carbazole

: 1421060-73-2
chloro{3,6-di-tert-butyl-1,8-bis-((diphenylphosphino)methyl)carbazole}palladium(II)

Guidance literature:: Multi-step reaction with 6 steps

1.1: n-butyllithium / diethyl ether; hexane / 2 h / 0 - 20 °C / Inert atmosphere

2.1: tert.-butyl lithium / diethyl ether; pentane / -78 - 20 °C / Inert atmosphere

2.2: 55 °C / Inert atmosphere

3.1: phosphorus tribromide / dichloromethane / 1 h / 0 °C / Inert atmosphere

4.1: n-butyllithium / hexane; tetrahydrofuran / 0.75 h / -78 °C / Inert atmosphere

4.2: -78 °C / Inert atmosphere

5.1: diethylamine / 96 h / Inert atmosphere

6.1: lithium diisopropyl amide / tetrahydrofuran / 1 h / 20 °C / Inert atmosphere

6.2: Inert atmosphere

With n-butyllithium; tert.-butyl lithium; phosphorus tribromide; diethylamine; lithium diisopropyl amide; In tetrahydrofuran; diethyl ether; hexane; dichloromethane; pentane;
DOI:10.1021/ic302454n

Reference yield:

: 1421060-69-6
3,6-di-tert-butyl-1,8-bis((diphenylphosphino)methyl)-9H-carbazole-bis(borane)

: 1421060-73-2
chloro{3,6-di-tert-butyl-1,8-bis-((diphenylphosphino)methyl)carbazole}palladium(II)

Guidance literature:: Multi-step reaction with 2 steps

1.1: diethylamine / 96 h / Inert atmosphere

2.1: lithium diisopropyl amide / tetrahydrofuran / 1 h / 20 °C / Inert atmosphere

2.2: Inert atmosphere

With diethylamine; lithium diisopropyl amide; In tetrahydrofuran;
DOI:10.1021/ic302454n