(η4-1,5-cycloctadiene)[η5-1-methoxycarbonyl-3,4-di(methoxycarbonylmethylene)cyclopentadienyl]cobalt

Base Information

Chemical Name:(η4-1,5-cycloctadiene)[η5-1-methoxycarbonyl-3,4-di(methoxycarbonylmethylene)cyclopentadienyl]cobalt
CAS No.:342370-96-1
Molecular Formula:C₂₁H₂₇CoO₆
Molecular Weight:434.435
Hs Code.:

Synonyms:(η4-1,5-cycloctadiene)[η5-1-methoxycarbonyl-3,4-di(methoxycarbonylmethylene)cyclopentadienyl]cobalt

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Chemical Property of (η4-1,5-cycloctadiene)[η5-1-methoxycarbonyl-3,4-di(methoxycarbonylmethylene)cyclopentadienyl]cobalt

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Technology Process of (η4-1,5-cycloctadiene)[η5-1-methoxycarbonyl-3,4-di(methoxycarbonylmethylene)cyclopentadienyl]cobalt

There total 1 articles about (η4-1,5-cycloctadiene)[η5-1-methoxycarbonyl-3,4-di(methoxycarbonylmethylene)cyclopentadienyl]cobalt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

: 26305-75-9
chlorotris(triphenylphosphine)cobalt(I)

: 342370-95-0
Li⁽¹⁺⁾*C₅H₂(CH₂COOCH₃)2(COOCH₃)^(1-)=LiC₅H₂(CH₂COOCH₃)2(COOCH₃)

: 5259-72-3,10060-40-9,111-78-4
cyclo-octa-1,5-diene

: 342370-96-1
(η4-1,5-cycloctadiene)[η5-1-methoxycarbonyl-3,4-di(methoxycarbonylmethylene)cyclopentadienyl]cobalt

Guidance literature:: In tetrahydrofuran; toluene; byproducts: (C6H5)3P, LiCl; (Ar); addn. of a soln. of lithium salt in THF to a soln. of cobalt complex and ligand in toluene, stirring at room temp. for 1 h, heating at 80°C for 1 h; filtration through a short column of alumina, concn., addn. of hexane, standing overnight, filtration, column chromy (Al2O3, hexane/EtOAc 8:2), evapn., dissolving in hexane/CH2Cl2 3:1 vol., freezing, recrystn. (hexane/CH2Cl2 3:1 vol.); elem. anal.;
DOI:10.1016/S0022-328X(00)00652-5