1-{[(1-phenyl-1H-tetrazol-5-yl)thio]methyl}-1H-naphtho[2,3-d][1,2,3]triazole-4,9-dione

Base Information

Chemical Name:1-{[(1-phenyl-1H-tetrazol-5-yl)thio]methyl}-1H-naphtho[2,3-d][1,2,3]triazole-4,9-dione
CAS No.:1449194-89-1
Molecular Formula:C₁₈H₁₁N₇O₂S
Molecular Weight:389.397
Hs Code.:

Synonyms:1-{[(1-phenyl-1H-tetrazol-5-yl)thio]methyl}-1H-naphtho[2,3-d][1,2,3]triazole-4,9-dione

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Chemical Property of 1-{[(1-phenyl-1H-tetrazol-5-yl)thio]methyl}-1H-naphtho[2,3-d][1,2,3]triazole-4,9-dione

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Technology Process of 1-{[(1-phenyl-1H-tetrazol-5-yl)thio]methyl}-1H-naphtho[2,3-d][1,2,3]triazole-4,9-dione

There total 5 articles about 1-{[(1-phenyl-1H-tetrazol-5-yl)thio]methyl}-1H-naphtho[2,3-d][1,2,3]triazole-4,9-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 1449194-80-2
1-{[(1-phenyl-1H-tetrazol-5-yl)thio]methyl}-1H-naphtho[2,3-d][1,2,3]triazole

: 1449194-89-1
1-{[(1-phenyl-1H-tetrazol-5-yl)thio]methyl}-1H-naphtho[2,3-d][1,2,3]triazole-4,9-dione

Guidance literature:: With chromium(VI) oxide; periodic acid; In acetonitrile; at 20 ℃; for 3h; Inert atmosphere;
DOI:10.1021/ol401661j

Reference yield:

: 5-[(chloromethyl)thio]-1-phenyl-1H-tetrazole

: 1449194-89-1
1-{[(1-phenyl-1H-tetrazol-5-yl)thio]methyl}-1H-naphtho[2,3-d][1,2,3]triazole-4,9-dione

Guidance literature:: Multi-step reaction with 4 steps

1: sodium iodide / acetone / 4 h / Reflux

2: sodium azide / N,N-dimethyl-formamide / 4 h / 50 °C

3: 18-crown-6 ether; potassium fluoride / acetonitrile / 7 h / 20 °C / Inert atmosphere

4: periodic acid; chromium(VI) oxide / acetonitrile / 3 h / 20 °C / Inert atmosphere

With chromium(VI) oxide; potassium fluoride; sodium azide; 18-crown-6 ether; periodic acid; sodium iodide; In N,N-dimethyl-formamide; acetone; acetonitrile;
DOI:10.1021/ol401661j

Reference yield:

: 1449194-55-1
5-[(azidomethyl)thio]-1-phenyl-1H-tetrazole

: 1449194-89-1
1-{[(1-phenyl-1H-tetrazol-5-yl)thio]methyl}-1H-naphtho[2,3-d][1,2,3]triazole-4,9-dione

Guidance literature:: Multi-step reaction with 2 steps

1: 18-crown-6 ether; potassium fluoride / acetonitrile / 7 h / 20 °C / Inert atmosphere

2: periodic acid; chromium(VI) oxide / acetonitrile / 3 h / 20 °C / Inert atmosphere

With chromium(VI) oxide; potassium fluoride; 18-crown-6 ether; periodic acid; In acetonitrile;
DOI:10.1021/ol401661j