Mo(CO)5((C₆H₅)2PCH₂CCHC(O)OC(CH₃)2O)

Base Information

Chemical Name:Mo(CO)5((C₆H₅)2PCH₂CCHC(O)OC(CH₃)2O)
CAS No.:155208-34-7
Molecular Formula:C₂₄H₁₉MoO₈P
Molecular Weight:562.324
Hs Code.:

Mo(CO)5((C<sub>6</sub>H<sub>5</sub>)2PCH<sub>2</sub>CCHC(O)OC(CH<sub>3</sub>)2O)

Synonyms:Mo(CO)5((C₆H₅)2PCH₂CCHC(O)OC(CH₃)2O)

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Chemical Property of Mo(CO)5((C₆H₅)2PCH₂CCHC(O)OC(CH₃)2O)

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Technology Process of Mo(CO)5((C₆H₅)2PCH₂CCHC(O)OC(CH₃)2O)

There total 1 articles about Mo(CO)5((C₆H₅)2PCH₂CCHC(O)OC(CH₃)2O) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.1%

: 23581-74-0
(chlorodiphenylphosphine)pentacarbonylmolybdenum(0)

: 5394-63-8
2,2,6-trimethyl-4H-1,3-dioxin-4-one

: 108-18-9
diisopropylamine

: 155208-34-7
Mo(CO)5((C₆H₅)2PCH₂CCHC(O)OC(CH₃)2O)

Guidance literature:: With n-butyllithium; In tetrahydrofuran; N2; n-butyllithium in hexane added slowly to soln. of amine at -78°C; stirred for 10 min; soln. of dioxin added slowly; stirred for 30 min; added slowly to soln. of Mo-complex; coolig bath removed;; H2O added slowly; evapd.; treated with Et2O and water; ppt. at 10°C; recrystd. from CH2Cl2/hexane; elem. anal.;;
DOI:10.1016/S0277-5387(00)86596-1

Reference yield: 75.0%

: 155208-34-7
Mo(CO)5((C₆H₅)2PCH₂CCHC(O)OC(CH₃)2O)

: 155230-51-6
Mo(CO)5((C₆H₅)2PCH₂C(O)CH₂COOCH₃)

Guidance literature:: With methanol; n-butyllithium; In tetrahydrofuran; N2; n-BuLi in hexane added slowly to MeOH; stirred for 15 min; added slowly to soln. of complex; stirred for 18 h;; evapd., dissolved in Et2O/H2O; organic layer washed with H2O; dried (MgSO4); filtered through SiO2; evapd.; recrystd. from hexane; elem. anal.;;
DOI:10.1016/S0277-5387(00)86596-1

Reference yield: 62.0%

: 107-03-9
1-thiopropane

: 155208-34-7
Mo(CO)5((C₆H₅)2PCH₂CCHC(O)OC(CH₃)2O)

: 155208-36-9
Mo(CO)5((C₆H₅)2PCH₂C(O)CH₂COSCH₂CH₂CH₃)

Guidance literature:: With n-butyllithium; In tetrahydrofuran; N2; n-BuLi in hexane and n-propylmercaptane stirred for 30 min; added to soln. of complex; stirred for 24 h;; evapd., washed with CH2Cl2/hexane; evapd.; dissolved in Et2O/hexane; filtered through SiO2; evapd.; concd. (N2-stream); hexane added; concd.; crystd. at -10°C; identified by mass spectroscopy;;
DOI:10.1016/S0277-5387(00)86596-1